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Graphene decorated ...
Graphene decorated with metal nanoparticles : Hydrogen sorption and related artefacts
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- Klechikov, Alexey (author)
- Umeå universitet,Institutionen för fysik
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- Sun, Jinhua (author)
- Umeå universitet,Institutionen för fysik
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- Hu, Guangzhi (author)
- Umeå universitet,Institutionen för fysik
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Zheng, Mingbo (author)
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- Wågberg, Thomas (author)
- Umeå universitet,Institutionen för fysik
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- Talyzin, Alexandr V., 1969- (author)
- Umeå universitet,Institutionen för fysik
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(creator_code:org_t)
- Elsevier BV, 2017
- 2017
- English.
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In: Microporous and Mesoporous Materials. - : Elsevier BV. - 1387-1811 .- 1873-3093. ; 250, s. 27-34
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https://umu.diva-por... (primary) (Raw object)
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http://umu.diva-port...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Hydrogen sorption by reduced graphene oxides (r-GO) is not found to increase after decoration with Pd and Pt nanoparticles. Treatments of metal decorated samples using annealing under hydrogen or air were tested as a method to create additional pores by effects of r-GO etching around nanoparticles. Increase of Specific Surface Area (SSA) was observed for some air annealed r-GO samples. However, the same treatments applied to activated r-GO samples with microporous nature and higher surface area result in breakup of structure and dramatic decrease of SSA. Our experiments have not revealed effects which could be attributed to spillover in hydrogen sorption on Pd or Pt decorated graphene. However, we report irreversible chemisorption of hydrogen for some samples which can be mistakenly assigned to spillover if the experiments are incomplete.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Keyword
- Graphene
- Hydrogen storage
- Graphene oxide
- Nanoparticles
- Decoration
Publication and Content Type
- ref (subject category)
- art (subject category)
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