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Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?

Shukla, Shashi Kant, 1983- (author)
Umeå universitet,Kemiska institutionen
Nikjoo, Dariush (author)
Mikkola, Jyri-Pekka (author)
Umeå universitet,Kemiska institutionen
 (creator_code:org_t)
The Royal Society of Chemistry, 2020
2020
English.
In: Physical Chemistry, Chemical Physics - PCCP. - : The Royal Society of Chemistry. - 1463-9076 .- 1463-9084. ; 22:3, s. 966-970
  • Journal article (peer-reviewed)
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  • A critical analysis of the role of Hammett basicity (H−) and aqueous basicity (pKa) in CO2 uptake in deep-eutectic solvents (DESs) suggests that neither H− nor pKa correlates with the CO2 w/w% capacity in the studied DESs. Instead, strong “synergistic interactions” between donor and acceptor moieties satisfactorily relate to the w/w% of CO2 in DESs.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Naturresursteknik -- Annan naturresursteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Environmental Engineering -- Other Environmental Engineering (hsv//eng)
TEKNIK OCH TEKNOLOGIER  -- Naturresursteknik -- Energisystem (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Environmental Engineering -- Energy Systems (hsv//eng)

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