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High pressure and h...
High pressure and high temperature induced polymerization of C60 solvates : The effect of intercalated aromatic solvents
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Du, Mingrun (author)
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Dong, Jiajun (author)
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Zhang, Ying (author)
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- Sundqvist, Bertil (author)
- Umeå universitet,Institutionen för fysik
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- Andersson, Ove (author)
- Umeå universitet,Institutionen för fysik
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Liu, Bingbing (author)
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Wang, Mingchao (author)
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Li, Zepeng (author)
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Wei, Tong (author)
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Zhou, Qingjun (author)
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Yang, Xiong (author)
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(creator_code:org_t)
- 2021-07-28
- 2021
- English.
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In: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 125:31, s. 17155-17163
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- The polymerization of three typical aromatic solvent-doped fullerene materials with similar hexagonal closest packed (hcp) structures (mesitylene/C60, m-dichlorobenzene/C60 and m-xylene/C60 solvates) is studied under high pressure and high temperature (HPHT, 1.5 GPa, 573 K and 2 GPa, 700 K, respectively). Raman and photoluminescence spectroscopies reveal that the intercalated aromatic solvents play a crucial role in tailoring the extent of polymerization of C60 molecules. In the solvates, the solvents confine formation of covalent bonds between C60 molecules to the 001 direction and the (001) plane of the hcp lattices, leading to the formation of mixed polymeric phases of monomers, dimers, one-dimensional (1D) chainlike oligomers, and two-dimensional (2D) tetragonal phase polymers under suitable HPHT conditions. The type and number of substituent groups of the aromatic solvents are found to have significant influence, determining the amounts and types of polymeric phases formed. Our studies enrich the understanding of the formation mechanisms for controllably fabricating polymeric fullerenes and facilitate targeted design and synthesis of unique fullerene-based carbon materials.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Du, Mingrun
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Dong, Jiajun
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Zhang, Ying
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Sundqvist, Berti ...
-
Andersson, Ove
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Liu, Bingbing
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show more...
-
Wang, Mingchao
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Li, Zepeng
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Wei, Tong
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Zhou, Qingjun
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Yang, Xiong
-
show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Physical Chemist ...
- Articles in the publication
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The Journal of P ...
- By the university
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Umeå University