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Developing insolubl...
Developing insoluble polyoxometalate clusters to bridge homogeneous and heterogeneous water oxidation photocatalysis
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- Hu, Qiyu (author)
- College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
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- Chen, Shoushun (author)
- College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
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- Wågberg, Thomas, 1971- (author)
- Umeå universitet,Institutionen för fysik
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- Zhou, Hongshan (author)
- College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
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- Li, Shujun (author)
- School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, China
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- Li, Yiding (author)
- Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, School of Materials & Energy, Lanzhou University, Lanzhou, China
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- Tan, Yilan (author)
- College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
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- Hu, Wenqi (author)
- College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
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- Ding, Yong (author)
- College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
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- Han, Xinbao (author)
- College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
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(creator_code:org_t)
- John Wiley & Sons, 2023
- 2023
- English.
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In: Angewandte Chemie International Edition. - : John Wiley & Sons. - 1433-7851 .- 1521-3773. ; 2:32
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Cluster catalysts are attractive for their atomically precise structures, defined compositions, tunable coordination environments, uniform active sites, and their ability to transfer multiple electrons, but they suffer from poor stability and recyclability. Here, we report a general approach to the direct insolubilization of a water soluble polyoxometalate (POM) [{(B-α-PW9O34)Co3(OH)(H2O)2(O3PC(O)-(C3H6NH3)PO3)}2Co]14- (Co7) and formation of a series of POM-based solid catalysts with the counter-cations Ag+, Cs+, Sr2+, Ba2+, Pb2+, Y3+, and Ce3+. They exhibit improved catalytic activities for visible-light-driven water oxidation following the trend CsCo7>SrCo7>AgCo7>CeIII Co7>BaCo7>YCo7>PbCo7. While CsCo7 exhibits mainly homogeneous catalysis, the others are predominantly heterogeneous catalysts. An optimal oxygen yield of 41.3 % and a high apparent quantum yield (AQY) of 30.6 % for SrCo7 is obtained, which is comparable to that of the parent homogeneous POM. Band gap structures, UV/Vis spectra, and real-time laser flash photolysis experiments collectively suggest that easier electron transfer from the solid POM catalyst to the photosensitizer promotes photocatalytic water oxidation performance. These solid POM catalysts exhibit good stability, which is directly confirmed by a combination of Fourier-transform infrared spectroscopy, electron microscopy, X-ray diffraction patterns, Raman spectroscopy, X-ray photoelectron spectroscopy, five cycles of tests, and poisoning experiments.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Cluster-Based Solid Catalysts
- Cobalt
- Photocatalysis
- Structure–Activity Relationships
- Water Oxidation
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Hu, Qiyu
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Chen, Shoushun
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Wågberg, Thomas, ...
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Zhou, Hongshan
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Li, Shujun
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Li, Yiding
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show more...
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Tan, Yilan
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Hu, Wenqi
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Ding, Yong
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Han, Xinbao
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Inorganic Chemis ...
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Angewandte Chemi ...
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Umeå University