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Molecular rotation ...
Molecular rotation in C70 at high pressures: a thermal conductivity study
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- Soldatov, Alexander (author)
- Umeå universitet,Institutionen för fysik
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- Sundqvist, Bertil (author)
- Umeå universitet,Institutionen för fysik
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(creator_code:org_t)
- Elsevier Science Ltd, 1996
- 1996
- English.
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In: Journal of Physics and Chemistry of Solids. - : Elsevier Science Ltd. - 0022-3697 .- 1879-2553. ; 57:9, s. 1371-1375
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- We have measured the thermal conductivity ε and the heat capacity per unit volume varrhocp of highly pure C70 in the temperature interval 100–450 K under pressures up to 1 GPa. Anomalies indicating freezing of uniaxial molecular rotation were observed in λ and varrhocp upon both cooling and increasing pressure. The phase boundary for this transition has an approximate slope dT/dp = 70 K Gpa−1. The temperature and pressure dependence of λ indicate a substantial amount of structural defects in the sample and strong metastability effects.
Subject headings
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
- NATURVETENSKAP -- Fysik -- Annan fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Other Physics Topics (hsv//eng)
Keyword
- Fullerenes
- C70
- high pressure
- thermal conductivity
- molecular orientation
- molecular rotation
- uniaxial rotation
- phase diagram
- Condensed matter physics
- Kondenserade materiens fysik
- fysik
- Physics
- Fysik
Publication and Content Type
- ref (subject category)
- art (subject category)
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