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Transport study of ...
Transport study of (T,p) phase diagram in PdAl2Cl8 intercalated graphite
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McRae, Edward (author)
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- Andersson, Odd E. (author)
- Umeå universitet,Institutionen för fysik
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Lelaurain, Michelle (author)
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Polo, V. (author)
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- Sundqvist, Bertil (author)
- Umeå universitet,Institutionen för fysik
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Vangelisti, René (author)
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(creator_code:org_t)
- Elsevier Ltd. 1996
- 1996
- English.
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In: Journal of Physics and Chemistry of Solids, volume 57, issues 6-8. - : Elsevier Ltd.. ; , s. 827-831
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- We have examined the c-direction variations of resistance, Rc (or resistivity, varrhoc) over the 4.2–295 K. temperature range at ambient pressure, and over the 160–295 K range for pressures up to 1.5 GPa on first stage PdAl2Cl8 graphite intercalation compounds. All samples examined manifest a rapid, nonlinear decrease in Rc with pressure (maximum ¦dln Rc/dp¦ > 300 % GPa−1 at 0.4 GPa. The overall Rc decrease is around 90% by 1GPa, a value greater than that observed in any other GIC to date. Upon slow pressure release, the resistance increases linearly but to only about 20–25% of its initial (1 bar) value for HOPG-based materials: on the contrary, it returns along its initial R-p trajectory for GICs based on single crystal graphite. We discuss these data with reference to the X-ray diffraction results, to the significance of the residual resistivity and to studies on other similar lamellar solids.
Subject headings
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Keyword
- Graphite intercalation compound
- GIC
- insertion compound
- PdAl2Cl8
- structural phase diagram
- resistivity
- c-axis resistance
- high pressure
- low temperature
- HOPG
- single crystal graphite
- Condensed matter physics
- Kondenserade materiens fysik
- fysik
- Physics
Publication and Content Type
- ref (subject category)
- kon (subject category)
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