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Influence of TiO2 additive on vaporisation of potassium during straw combustion

Wiinikka, Henrik (author)
RISE,SP Energy Technology Center
Grönberg, Carola (author)
RISE,SP Energy Technology Center
Öhrman, Olov (author)
RISE,SP Energy Technology Center
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Boström, Dan (author)
Umeå universitet,Energiteknik och termisk processkemi
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 (creator_code:org_t)
American Chemical Society (ACS), 2009
2009
English.
In: Energy & Fuels. - : American Chemical Society (ACS). - 0887-0624 .- 1520-5029. ; 23:11, s. 5367-5374
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • In this work, the influence of TiO2 on the vaporization of K during combustion of straw under fixed bed condition was investigated experimentally. Controlled combustion experiments with a varied amount of TiO2 in straw pellets were performed in an 8 kW pellet burner together with sampling of particles (impactor and absolute filter), analysis of the flue gas composition (Fourier transform infrared, FTIR), and chemical analyses of the collected particles and bottom ash (inductively coupled plasma-atomic emission spectroscopy (ICP-AES), scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS), and X-ray diffraction (XRD)). The experimental results showed that the vaporization of K from the fuel bed was significantly reduced when TiO2 was used as an additive. The vaporization of K was reduced by ~40−50% for an optimal amount of TiO2 additive. The optimal added TiO2 for the straw used in this work corresponds to a Ti/K (wt) ratio between ~0.6−1.0. If more TiO2 was added to the fuel, the release of K to the gas phase was not further reduced and unreacted TiO2 was found in the bottom ash.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Naturresursteknik -- Energisystem (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Environmental Engineering -- Energy Systems (hsv//eng)
TEKNIK OCH TEKNOLOGIER  -- Kemiteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Chemical Engineering (hsv//eng)
TEKNIK OCH TEKNOLOGIER  -- Maskinteknik -- Energiteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Mechanical Engineering -- Energy Engineering (hsv//eng)

Keyword

Energiteknik

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By the author/editor
Wiinikka, Henrik
Grönberg, Carola
Öhrman, Olov
Boström, Dan
About the subject
ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
and Environmental En ...
and Energy Systems
ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
and Chemical Enginee ...
ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
and Mechanical Engin ...
and Energy Engineeri ...
Articles in the publication
Energy & Fuels
By the university
Umeå University
RISE

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