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Modular pressurized...
Modular pressurized liquid extraction for simultaneous extraction, clean-up and fractionation of PCDD/Fs in soil, sediment and sludge samples
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- Do, Lan (author)
- Umeå universitet,Kemiska institutionen
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- Xuan, Thong H. (author)
- Umeå universitet,Kemiska institutionen
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- Lundstedt, Staffan (author)
- Umeå universitet,Kemiska institutionen
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- Haglund, Peter (author)
- Umeå universitet,Kemiska institutionen,EcoChange
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(creator_code:org_t)
- RSC Publishing, 2013
- 2013
- English.
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In: Analytical Methods. - : RSC Publishing. - 1759-9660 .- 1759-9679. ; :5, s. 1231-1237
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Modular pressurized liquid extraction (M-PLE) procedures were developed for simultaneous extraction, clean-up and fractionation of polychlorinated dioxins and furans (PCDD/Fs) in soil, sediment and sludge samples. The procedures utilize two coupled extraction cells: an upstream cell filled with the sample and layers of silica and acid- and base-modified silica, and a downstream cell filled with activated carbon. The silica layers were added to remove polar or hydrolysable matrix components, and the carbon to perform planarity-based fractionation. Two solvent systems (dichloromethane–heptane, DCM–Hp and diethyl ether–heptane, DEE–Hp) and two activated carbon loads (1% and 3% carbon on Celite) were evaluated using certified reference materials (CRM-529 and WMS-01) and materials from previous inter-calibration studies. Using any of the four procedures, data statistically equivalent to the certified or reference values were obtained. The M-PLE procedure using DCM–Hp and 1% carbon sometimes extracted the reference materials more efficiently than the reference methods, while the DEE–Hp procedure extracted them equally efficient, offering an alternative with less environmental impact. The methods with 1% carbon on Celite produced sufficiently pure extracts for sample loads up to one gram, but for greater sample loads the higher carbon load (3% carbon on Celite) was required to avoid breakthrough of target analytes. The new streamlined procedures are fast, cost-efficient, involve relatively low environmental impact (in the case of DEE–Hp) and are well suited for high-throughput analysis of solid samples, e.g. in connection with environmental monitoring campaigns and major soil remediation efforts.
Subject headings
- NATURVETENSKAP -- Kemi -- Analytisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Analytical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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