Search: onr:"swepub:oai:DiVA.org:umu-9089" >
Self-Organization o...
Self-Organization of Highly Stable Electron Donor-Acceptor Complexes via Host-Guest Interactions
-
Ushakov, Evgeny N (author)
-
Gromov, Sergey P (author)
-
Vedernikov, Artem I (author)
-
show more...
-
Malysheva, Ekaterina V (author)
-
Botsmanova, Asya A (author)
-
Alfimov, Michael V (author)
-
- Eliasson, Bertil (author)
- Umeå universitet,Kemiska institutionen
-
- Edlund, Ulf (author)
- Umeå universitet,Kemiska institutionen
-
Whitesell, James K (author)
-
Fox, Marye Anne (author)
-
show less...
-
(creator_code:org_t)
- 2001-10-25
- 2002
- English.
-
In: The Journal of Physical Chemistry A. - : American Chemical Society (ACS). - 1089-5639 .- 1520-5215. ; 106:10, s. 2020-3
- Related links:
-
https://urn.kb.se/re...
-
show more...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- Biscrown stilbene S forms complexes of 1:1 and 2:1 composition with bisammonium viologen salt V4+ in acetonitrile solution. Both of the complexes exhibit spectroscopic behavior typical of molecular electron donor-acceptor complexes. The 1:1 complex [S·V]4+ has a very high thermodynamic stability (log K = 9.08), which is due to simultaneous interaction of the two ammonium groups of V4+ with the two 18-crown-6-ether units of S. The 2:1 complex (log K = 12.28) [S·V·S]4+ likely has a sandwich-type layered structure in which the acceptor salt is located between two complexed molecules of the biscrown stilbene.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database
- By the author/editor
-
Ushakov, Evgeny ...
-
Gromov, Sergey P
-
Vedernikov, Arte ...
-
Malysheva, Ekate ...
-
Botsmanova, Asya ...
-
Alfimov, Michael ...
-
show more...
-
Eliasson, Bertil
-
Edlund, Ulf
-
Whitesell, James ...
-
Fox, Marye Anne
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
- Articles in the publication
-
The Journal of P ...
- By the university
-
Umeå University