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High-temperature ca...
High-temperature cation ordering in olivine : an in situ Mossbauer study of synthetic (Mg0.55Fe0.45)(2) SiO4
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- Abdu, Y. A. (author)
- Uppsala universitet,Institutionen för geovetenskaper
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- Annersten, H. (author)
- Uppsala universitet,Institutionen för geovetenskaper
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- Ericsson, T. (author)
- Uppsala universitet,Institutionen för geovetenskaper
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Hawthorne, F. C. (author)
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(creator_code:org_t)
- 2008-11-01
- 2008
- English.
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In: Hyperfine Interactions. - : Springer Science and Business Media LLC. - 0304-3843 .- 1572-9540. ; 186:1-3, s. 99-103
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- High- temperature in situ Mossbauer spectroscopy measurements ( 300 950. C) were done on synthetic olivine of composition ( Mg0.55Fe0.45) 2 SiO4 (= Fa45) in order to study the distribution of Fe2+ over the M1 and M2 octahedral sites. The spectra are fit with two doublets, which are assigned to Fe2+ at the M1 ( smaller splitting) and M2 sites. The Fe2+ site- occupancies at M1 and M2, obtained from the Mossbauer relative areas, suggest that Fe2+ has a slight preference for the M1 site at temperatures below similar to 500. C, with a tendency of disordering around this temperature. At higher temperatures, Fe2+ again prefers to occupy the M1 site, where it shows a considerable order at this site up to 750C. At still higher temperatures, the spectra indicated partial reduction of the Fa- component into metallic iron and the resolution of the doublets was severely deteriorated.
Subject headings
- NATURVETENSKAP -- Geovetenskap och miljövetenskap (hsv//swe)
- NATURAL SCIENCES -- Earth and Related Environmental Sciences (hsv//eng)
Keyword
- Mossbauer spectroscopy
- Olivine
- High-temperature
- Cation-ordering
- Earth sciences
- Geovetenskap
Publication and Content Type
- ref (subject category)
- art (subject category)
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