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Tetraethylammonium ...
Tetraethylammonium [12,12-diethyl-2,2,9,9-tetramethyl-1,4,7,10-tetraza-5,6-benzotridecane-3 ,8,11,13-tetraone(4-)]oxidomanganate(V)
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- Berggren, Gustav (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
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Kaynak, F. B. (author)
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- Anderlund, Magnus F. (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
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- Eriksson, Lars (author)
- Stockholms universitet,Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi
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- Åkermark, Björn (author)
- Stockholms universitet,Institutionen för organisk kemi
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(creator_code:org_t)
- 2007
- 2007
- English.
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In: Acta Crystallographica Section E. - 1600-5368. ; 63:11, s. M2672-M2673
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Subject headings
Close
- The Mn-V complex in the title compound, (C8H20N)[ Mn(C21H26N4O4)O], is interesting as it has been suggested that Mn-V oxospecies are intermediates both in epoxidation of alkenes and in water oxidation in PSII, i.e. photosystem II, the protein found in oxygenic photosynthetic organisms, which uses light to split water into O-2, protons and electrons. The Mn atom has a square-pyramidal coordination of four N atoms with an apical O atom. The four N atoms coordinating to Mn [Mn-N = 1.872 (2)-1.882 (2) angstrom] form a plane within 0.03 (3) angstrom from which the Mn ion is displaced by 0.582 (2) angstrom.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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