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Solution structure ...
Solution structure of a seven coordinated manganese(II) complex via electrospray ionization mass spectrometry
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Najafpour, Mohammad Mahdi (author)
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Boghaei, Davar M. (author)
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- Sjöberg, Per J.R. (author)
- Uppsala universitet,Analytisk kemi
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(creator_code:org_t)
- Elsevier BV, 2010
- 2010
- English.
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In: Spectrochimica Acta Part A - Molecular and Biomolecular Spectroscopy. - : Elsevier BV. - 1386-1425 .- 1873-3557. ; 75:3, s. 1168-1170
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The mononuclear complex [Mn(tptz)(CH3COO)(OH2)2]NO3 (1) was investigated by electrospray ionization mass spectrometry in aqueous solution at pH 4.5. Electrospray ionization mass spectrometry shows that mononuclear and dinuclear manganese cationic species are present in solution, probably in equilibrium with neutral 1. An experiment showed that the most important reaction in the presence of oxone (2KHSO5·KHSO4·K2SO4) is decoordination.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Manganese
- Oxygen evolving complex
- ESI(+)-MS/MS
- tptz
- Chemistry
- Kemi
- Analytical Chemistry
- Analytisk kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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