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Cyclometalated Ru-I...
Cyclometalated Ru-II Complexes with Improved Octahedral Geometry : Synthesis and Photophysical Properties
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- Jäger, Michael (author)
- Uppsala universitet,Molekylär biomimetik
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- Smeigh, Amanda (author)
- Uppsala universitet,Kemisk fysik
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- Lombeck, Florian (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
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Gorls, Helmar (author)
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Collin, Jean-Paul (author)
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Sauvage, Jean-Pierre (author)
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- Hammarström, Leif (author)
- Uppsala universitet,Kemisk fysik
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- Johansson, Olof (author)
- Uppsala universitet,Molekylär biomimetik
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(creator_code:org_t)
- 2009-12-10
- 2010
- English.
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In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 49:2, s. 374-376
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Cyclometalated bis-tridentate ruthenium(II) complexes incorporating 2,6-diquinolin-8-ylpyridine ligands and exhibiting broad visible absorptions are described. A [Ru(N boolean AND N boolean AND N)(N boolean AND C boolean AND N)](+) complex based only on ligands with expanded bite angles has a metal-to-ligand charge-transfer excited-state lifetime of 16 ns, which is attributed to a strong ligand field and therefore reduced deactivation via metal-centered states.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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