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Probing the valence...
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Feifel, RaimundUppsala universitet,Fysik II
(author)
Probing the valence character of O-1s -> Rydberg excited O-2 by participator Auger decay measurements and partial ion yield spectroscopy following x-ray absorption
- Article/chapterEnglish2007
Publisher, publication year, extent ...
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AIP Publishing,2007
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:uu-144709
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-144709URI
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https://doi.org/10.1063/1.2723745DOI
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https://lup.lub.lu.se/record/662606URI
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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The valence character of O 1s -> Rydberg excited O-2 is investigated by means of participator Auger decay spectroscopy, performed at selected photon energies across the K-shell resonance region, and by means of partial ion yield x-ray absorption spectroscopy. For several of the excitation energies studied, the authors find substantial sigma(*)((4)Sigma(-)(u),(2)Sigma(-)(u)) valence character being mixed with ns sigma and np sigma ((4)Sigma(-)(u),(2)Sigma(-)(u)) Rydberg states. An experimental indication of a coupling between the channels associated with quartet and doublet ion cores is considered and discussed. New spectroscopic constants are derived for the singly ionized X (2)Pi(g) state of O-2 based on the observation of at least 20 vibrational sublevels.
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Tanaka, T.
(author)
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Kitajima, M.
(author)
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Tanaka, H.
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De Fanis, A.
(author)
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Sankari, R.
(author)
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Karlsson, L.Uppsala universitet,Fysik II
(author)
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Ristinmaa Sörensen, StaceyLund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)slju-sri
(author)
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Piancastelli, Maria NovellaUppsala universitet,Fysik V
(author)
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Prümper, G.
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Hergenhahn, U.
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Ueda, K.
(author)
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Uppsala universitetFysik II
(creator_code:org_t)
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In:Journal of Chemical Physics: AIP Publishing126:17, s. 174304-0021-96061089-7690
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Feifel, Raimund
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Tanaka, T.
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Kitajima, M.
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Tanaka, H.
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De Fanis, A.
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Sankari, R.
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Karlsson, L.
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Ristinmaa Sörens ...
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Piancastelli, Ma ...
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Prümper, G.
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Hergenhahn, U.
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Ueda, K.
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NATURAL SCIENCES
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Uppsala University
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Lund University