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- Höglin, ViktorUppsala universitet,Oorganisk kemi (author)
The crystal and magnetic structure of the magnetocaloric compound FeMnP0.5Si0.5
- Article/chapterEnglish2011
Publisher, publication year, extent ...
- Elsevier BV,2011
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:uu-159482
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-159482URI
- https://doi.org/10.1016/j.jssc.2011.06.019DOI
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- Language:English
- Summary in:English
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Notes
- The crystal and magnetic structure of the magnetocaloric compound FeMnP0.5Si0.5 has been studied by means of neutron and X-ray powder diffraction. Single phase samples of nominal composition FeMnP0.5Si0.5 have been prepared by the drop synthesis method. The compound crystallizes in the Fe2P-type structure (P-62m) with the magnetic moments aligned along the a-axis. It is found that the Fe atoms are mainly situated in the tetrahedral 3g site while the Mn atoms prefer the pyramidal 3f position. The material is ferromagnetic (TC=382 K) and at 296 K the total magnetic moment is 4.4 µB/f.u. It is shown that the magnetic moment in the 3f site is larger (2.5 µB) than in the 3g site (1.9 µB).
Subject headings and genre
- NATURVETENSKAP Kemi Oorganisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Inorganic Chemistry hsv//eng
- Magnetocaloric
- Neutron powder diffraction
- X-ray diffraction (XRD)
- Drop synthesis method
- Magnetic refrigeration
- Magnetic structure
- TECHNOLOGY
- TEKNIKVETENSKAP
- Inorganic chemistry
- Oorganisk kemi
- Kemi med inriktning mot oorganisk kemi
- Chemistry with specialization in Inorganic Chemistry
- Teknisk fysik med inriktning mot fasta tillståndets fysik
- Engineering Science with specialization in Solid State Physics
Added entries (persons, corporate bodies, meetings, titles ...)
- Hudl, MatthiasUppsala universitet,Fasta tillståndets fysik(Swepub:uu)mathu701 (author)
- Sahlberg, MartinUppsala universitet,Oorganisk kemi(Swepub:uu)masah021 (author)
- Nordblad, PerUppsala universitet,Fasta tillståndets fysik(Swepub:uu)pno26208 (author)
- Beran, PremyslNuclear Physics Institute, Academy of Sciences of the Czech Republic (author)
- Andersson, YvonneUppsala universitet,Oorganisk kemi(Swepub:uu)yvonande (author)
- Uppsala universitetOorganisk kemi (creator_code:org_t)
Related titles
- In:Journal of Solid State Chemistry: Elsevier BV184:9, s. 2434-24380022-45961095-726X
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