onr:"swepub:oai:DiVA.org:uu-169114"
Search: onr:"swepub:oai:DiVA.org:uu-169114" > Synthesis and photo...
- 1 of 1
- Previous record
- Next record
- To hitlist
Synthesis and photophysics of a novel photocatalyst for hydrogen production based on a tetrapyridoacridine bridging ligand
-
- Karnahl, Michael (author)
- Uppsala universitet,Molekylär biomimetik
- Kuhnt, Christian (author)
- Heinemann, Frank W. (author)
- show more...
- Schmitt, Michael (author)
- Rau, Sven (author)
- Popp, Juergen (author)
- Dietzek, Benjamin (author)
- show less...
- (creator_code:org_t)
- Elsevier BV, 2012
- 2012
- English.
- In: Chemical Physics. - : Elsevier BV. - 0301-0104 .- 1873-4421. ; 393:1, s. 65-73
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- Molecular photocatalysts allow for selectively tuning their function on a molecular level based on an in-depth understanding of their chemical and photophysical properties. This contribution reports the synthesis and photophysical characterization of the novel molecular photocatalyst [(tbbpy)(2)Ru(tpac)PdCl(2)](2+) RutpacPd (with tpac = tetrapyrido[3,2-a:2',3'-c:3 '',2 ''-h:2''',3'''-j]acridine) and its mononuclear building block. Furthermore, detailed photocatalytic activity measurements of RutpacPd are presented. The introduction of the tpac-ligand into the molecular framework offers a potential route to reduce the impact of water as compared to the well-studied class of RutpphzPd (with tpphz = tetrapyrido[3,2-a:2',3'-c:300,2 ''-h: 2''',3'''-j] phenazine) complexes. The distinct impact of water on the electron-transfer processes in tpphz-ligands stems from the possibility of water to form hydrogen bonds to the phenazine nitrogen atoms and will potentially reduced when replacing the phenazine by the acridine unit. The effect of this structural variation on the catalytic properties and the underlying ultrafast intramolecular charge transfer behavior will be discussed in detail.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Photocatalysis
- Ultrafast dynamics
- Molecular photocatalyst
- Impact of water on the catalytic properties
- Hydrogen
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Chemical Physics (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Karnahl, Michael
- Kuhnt, Christian
- Heinemann, Frank ...
- Schmitt, Michael
- Rau, Sven
- Popp, Juergen
- show more...
- Dietzek, Benjami ...
- show less...
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- Articles in the publication
- Chemical Physics
- By the university
- Uppsala University
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
