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Cascade Reactions F...
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Arkhypchuk, Anna I.Uppsala universitet,Molekylär biomimetik
(author)
Cascade Reactions Forming Highly Substituted, Conjugated Phospholes and 1,2-Oxaphospholes
- Article/chapterEnglish2012
Publisher, publication year, extent ...
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2012-06-22
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Wiley,2012
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Numbers
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LIBRIS-ID:oai:DiVA.org:uu-182042
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-182042URI
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https://doi.org/10.1002/anie.201202153DOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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The reaction of a phospha-Wittig–Horner reagent with diacetylenic ketones (see scheme) results in a cascade of reactions that can lead to both an oxaphosphole-terminated cumulene system and an alkene-bridged bis-phosphole. The reaction outcome is determined by the nature of the acetylene termini, with phenyl groups stabilizing a carbene intermediate that dimerizes to give the bis-phosphole product.
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Santoni, Marie-PierreUppsala universitet,Molekylär biomimetik(Swepub:uu)marsa976
(author)
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Ott, SaschaUppsala universitet,Molekylär biomimetik(Swepub:uu)saott499
(author)
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Uppsala universitetMolekylär biomimetik
(creator_code:org_t)
Related titles
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In:Angewandte Chemie International Edition: Wiley51:31, s. 7776-77801433-78511521-3773
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