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- Arkhypchuk, Anna I.Uppsala universitet,Molekylär biomimetik (author)
Cascade Reactions Forming Highly Substituted, Conjugated Phospholes and 1,2-Oxaphospholes
- Article/chapterEnglish2012
Publisher, publication year, extent ...
- 2012-06-22
- Wiley,2012
- printrdacarrier
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- LIBRIS-ID:oai:DiVA.org:uu-182042
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-182042URI
- https://doi.org/10.1002/anie.201202153DOI
Supplementary language notes
- Language:English
- Summary in:English
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Notes
- The reaction of a phospha-Wittig–Horner reagent with diacetylenic ketones (see scheme) results in a cascade of reactions that can lead to both an oxaphosphole-terminated cumulene system and an alkene-bridged bis-phosphole. The reaction outcome is determined by the nature of the acetylene termini, with phenyl groups stabilizing a carbene intermediate that dimerizes to give the bis-phosphole product.
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- acetylenes
- conjugation
- cumulenes
- phospha-Wittig
- reaction mechanisms
Added entries (persons, corporate bodies, meetings, titles ...)
- Santoni, Marie-PierreUppsala universitet,Molekylär biomimetik(Swepub:uu)marsa976 (author)
- Ott, SaschaUppsala universitet,Molekylär biomimetik(Swepub:uu)saott499 (author)
- Uppsala universitetMolekylär biomimetik (creator_code:org_t)
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- In:Angewandte Chemie International Edition: Wiley51:31, s. 7776-77801433-78511521-3773
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