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Non-enzymatic kinet...
Non-enzymatic kinetic resolution of 1,2-azidoalcohols using a planar-chiral DMAP derivative catalyst
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- Mesas-Sánchez, Laura (author)
- Uppsala universitet,Institutionen för kemi - BMC
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- Díaz-Álvarez, Alba Estrella (author)
- Uppsala universitet,Institutionen för kemi - BMC
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- Dinér, Peter (author)
- Uppsala universitet,Institutionen för kemi - BMC,Uppsala University
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(creator_code:org_t)
- Elsevier BV, 2013
- 2013
- English.
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In: Tetrahedron. - : Elsevier BV. - 0040-4020 .- 1464-5416. ; 69:2, s. 753-757
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Optically pure 1,2-azidoalcohols are widely used as precursors for other high value organic products. A non-enzymatic kinetic resolution procedure for the stereoselective synthesis of chiral 1,2-azidoalcohols from the readily available racemic counterparts has been developed, employing a planar-chiral DMAP derivative catalyst. Following this procedure, a range of aromatic 1,2-azidoalcohols was obtained in good selectivities (up to S=45) and high enantiomeric excess (up to 99% ee).
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Non-enzymatic kinetic resolution
- 1
- 2-Azidoalcohols
- Planar-chiral DMAP derivative catalyst
- Ferrocenyl catalyst
Publication and Content Type
- ref (subject category)
- art (subject category)
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