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- Ericsson, ToreUppsala universitet,Institutionen för geovetenskaper (author)
Vacancy ordering in FeTSes-FeTS8 solid solutions studied by Mössbauer, X-ray and magnetization techniques
- Article/chapterEnglish1994
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- 1994
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- LIBRIS-ID:oai:DiVA.org:uu-195529
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-195529URI
- https://doi.org/10.1007/BF02069165DOI
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- Language:English
- Summary in:English
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- International Conference on the Applications of the Mossbauer Effect (ICAME 93), VANCOUVER, CANADA, AUG 08-14, 1993
- Superstructures, due to cation vacancy ordering, form in the NiAs-related pseudobinary solid solution Fe7Se8-Fe7S8 close to both end compositions (Fe-7(SxSe1-x)(8) with x less than or equal to 0.15 and x greater than or equal to 0.85) during rapid cooling of quartz ampoules from 600 degrees C, according to X-ray diffractometry (XRD) and magnetization (SQUID) measurements. Mossbauer spectroscopy indicates local vacancy ordering in the whole interval, but XRD and SQUID data exclude long-range vacancy ordering when the anion proportion of sulphur is between 15% and 85%.
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- Amcoff, ÖrjanUppsala universitet,Berggrundsgeologi (author)
- Nordblad, PerUppsala universitet,Fasta tillståndets fysik (author)
- Uppsala universitetInstitutionen för geovetenskaper (creator_code:org_t)
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- In:Hyperfine Interactions90:1, s. 515-5200304-38431572-9540
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