onr:"swepub:oai:DiVA.org:uu-215613"
Search: onr:"swepub:oai:DiVA.org:uu-215613" > Mechanistic Insight...
- 1 of 1
- Previous record
- Next record
- To hitlist
Mechanistic Insights into the Pd-Catalyzed Direct Amination of Allyl Alcohols : Evidence for an Outer-sphere Mechanism Involving a Palladium Hydride Intermediate
-
- Sawadjoon, Supaporn (author)
- Uppsala universitet,Syntetisk organisk kemi
-
- Sjöberg, Per J R (author)
- Uppsala universitet,Analytisk kemi
-
- Orthaber, Andreas (author)
- Uppsala universitet,Molekylär biomimetik
- show more...
- show less...
- (creator_code:org_t)
- 2014-01-08
- 2014
- English.
- In: Chemistry - A European Journal. - : Wiley. - 0947-6539 .- 1521-3765. ; 20:6, s. 1520-1524
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- The mechanism of direct amination of allyl alcohol by a palladium triphenylphosphite complex has been explored. Labelling studies show that the reaction proceeds through a π-allylpalladium intermediate. A second-order dependence of reaction rate on allyl alcohol concentration was observed. Kinetic isotope effect studies and ESI-MS studies are in agreement with a reaction proceeding through a palladium hydride intermediate in which both O-H bond and C-O bond cleavages are involved in rate-determining steps. A stereochemical study supports an outer-sphere nucleophilic attack of the π-allylpalladium intermediate giving complete chiral transfer from starting material to product.
Subject headings
- NATURVETENSKAP -- Kemi -- Analytisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Analytical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Chemistry - A European Journal (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Sawadjoon, Supap ...
- Sjöberg, Per J R
- Orthaber, Andrea ...
- Matsson, Olle
- Samec, Joseph S ...
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Analytical Chemi ...
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Physical Chemist ...
- Articles in the publication
- Chemistry - A Eu ...
- By the university
- Uppsala University
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
