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An experimental and...
An experimental and theoretical investigation of the valence double photoionisation of the iodine molecule
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Edvardsson, D (author)
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Danielsson, A (author)
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- Karlsson, L (author)
- Uppsala universitet,Fysik II
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Eland, J H D (author)
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(creator_code:org_t)
- Elsevier BV, 2006
- 2006
- English.
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In: Chemical Physics. - : Elsevier BV. - 0301-0104 .- 1873-4421. ; 324:2-3, s. 674-678
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The double photoionisation spectrum of molecular iodine has been measured at three wavelengths by the TOF-PEPECO technique and is interpreted using relativistic molecular structure COSCI calculations of potential curves for a large number of electronic states connected to the three lowest groups of dissociation limits. The lowest double ionisation energy is 24.85 ± 0.02 eV (adiabatic) or 24.95 ± 0.02 eV (vertical). It is associated with the electronic state of . The double ionisation process is mainly direct, and positions and widths of the bands are well reproduced by the calculations.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Double photoionisation
- I2
- Coincidence technique
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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