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Synthesis and Prope...
Synthesis and Properties of Bis-Porphyrin Molecular Tweezers : Effects of Spacer Flexibility on Binding and Supramolecular Chirogenesis
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- Blom, Magnus, 1984- (author)
- Uppsala universitet,Syntetisk organisk kemi
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- Norrehed, Sara, 1982- (author)
- Uppsala universitet,Syntetisk organisk kemi
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- Andersson, Claes-Henrik (author)
- Uppsala universitet,Syntetisk organisk kemi
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- Huang, Hao (author)
- Uppsala universitet,Nanoteknologi och funktionella material
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- Light, Mark E. (author)
- Department of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, U.K
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- Bergquist, Jonas (author)
- Uppsala universitet,Analytisk kemi
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- Grennberg, Helena (author)
- Uppsala universitet,Fysikalisk-organisk kemi
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- Gogoll, Adolf, 1957- (author)
- Uppsala universitet,Syntetisk organisk kemi
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(creator_code:org_t)
- 2015-12-23
- 2016
- English.
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In: Molecules. - : MDPI AG. - 1431-5157 .- 1420-3049. ; 21:1
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Abstract
Subject headings
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- Abstract: Ditopic binding of various dinitrogen compounds to three bisporphyrin molecular tweezers with spacers of varying conformational rigidity, incorporating the planar ene-diyne (1), the helical stiff stilbene (2), or the semirigid glycoluril motif fused to the porphyrins (3) are compared. Binding constants Ka = 10^4 to 10^6 M^-1 reveal subtle differences between these tweezers, that are discussed in terms of porphyrin dislocation modes. Exciton coupled circular dichroism (ECCD) of complexes with chiral dinitrogen guests provides experimental evidence for the conformational properties of the tweezers. The results are further supported and rationalized by conformational analysis.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Bisporphyrin tweezers
- metalloporphyrins
- porphyrinoids
- host-guest chemistry
- supramolecular chemistry
- chirogenesis
- chirality transfer
- exciton coupled circular dichroism
- conformational analysis
- Chemistry with specialization in Organic Chemistry
- Kemi med inriktning mot organisk kemi
- Teknisk fysik med inriktning mot nanoteknologi och funktionella material
- Engineering Science with specialization in Nanotechnology and Functional Materials
Publication and Content Type
- ref (subject category)
- art (subject category)
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Blom, Magnus, 19 ...
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Norrehed, Sara, ...
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Andersson, Claes ...
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Huang, Hao
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Light, Mark E.
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Bergquist, Jonas
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Grennberg, Helen ...
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Gogoll, Adolf, 1 ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Organic Chemistr ...
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Molecules
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Uppsala University