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The electronic natu...
The electronic nature of the aglycone dictates the drive of the pseudorotational equilibrium of the pentofuranose moiety in C-nucleosides
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- Luyten, I (author)
- Uppsala universitet
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- Matulic-Adamic, J (author)
- Uppsala universitet
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- Beigelman, L (author)
- Uppsala universitet
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- Chattopadhyaya, J (author)
- Uppsala universitet
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(creator_code:org_t)
- MARCEL DEKKER INC, 1998
- 1998
- English.
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In: NUCLEOSIDES & NUCLEOTIDES. - : MARCEL DEKKER INC. - 0732-8311. ; 17:9-11, s. 1605-1611
- Related links:
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https://urn.kb.se/re...
Abstract
Subject headings
Close
- We herein show for the first time that the specific electronic character of a C-aglycone dictates the thermodynamic preference of the two-state N reversible arrow S pseudorotational equilibrium to either N- or S-type sugar. As the electron-deficiency of t
Keyword
- NMR COUPLING-CONSTANTS; SUBSTITUENT ELECTRONEGATIVITIES; SUGAR CONFORMATION; GAUCHE; EQUATION; THERMODYNAMICS; QUANTITATION; STRENGTH
Publication and Content Type
- vet (subject category)
- art (subject category)
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