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The strength of the anomeric effect in adenosine, guanosine, and in their 2'-deoxy counterparts is medium-dependent
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- Luyten, I (author)
- Uppsala universitet
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- Thibaudeau, C (author)
- Uppsala universitet
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- Chattopadhyaya, J (author)
- Uppsala universitet
- (creator_code:org_t)
- AMER CHEMICAL SOC, 1997
- 1997
- English.
- In: JOURNAL OF ORGANIC CHEMISTRY. - : AMER CHEMICAL SOC. - 0022-3263. ; 62:25, s. 8800-8808
- Journal article (other academic/artistic)
Abstract
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- In nucleosides, the anomeric effect (AE) (i.e. stereoelectronic n(O4')-->sigma*(C1'-N9) interactions) places the aglycon in the pseudoaxial orientation in the N-type conformation (2'-exo-3'-endo), whereas the inherent steric effect of the nucleobase oppos
Keyword
- NMR COUPLING-CONSTANTS; PSEUDOROTATIONAL EQUILIBRIUM; PENTOFURANOSE MOIETY; CONFORMATIONAL-ANALYSIS; SUBSTITUENT ELECTRONEGATIVITIES; SUGAR CONFORMATION; C-NUCLEOSIDES; DRIVE; GAUCHE; THERMODYNAMICS
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- art (subject category)
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