Search: onr:"swepub:oai:DiVA.org:uu-298905" >
Pb2MnTeO6 Double Pe...
Pb2MnTeO6 Double Perovskite : An Antipolar Anti-ferromagnet
-
- Retuerto, Maria (author)
- Rutgers State Univ, Dept Chem & Chem Biol, 610 Taylor Rd, Piscataway, NJ 08854 USA.;CSIC, Inst Catalisis & Petr Quim, Grp Energia & Quim Sostenibles EQS, C Marie Curie 2,L10, Madrid 28049, Spain.
-
- Skiadopoulou, Stella (author)
- Acad Sci Czech Republic, Inst Phys, Na Slovance 2, Prague 18221 8, Czech Republic.
-
- Li, Man-Rong (author)
- Rutgers State Univ, Dept Chem & Chem Biol, 610 Taylor Rd, Piscataway, NJ 08854 USA.
-
show more...
-
- Abakumov, Artem M. (author)
- Univ Antwerp, EMAT, Groenenborgerlaan 171, B-2020 Antwerp, Belgium.;Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia.
-
- Croft, Mark (author)
- Rutgers State Univ, Dept Phys & Astron, 136 Frelinghuysen Rd, Piscataway, NJ 08854 USA.
-
- Ignatov, Alexander (author)
- Rutgers State Univ, Dept Phys & Astron, 136 Frelinghuysen Rd, Piscataway, NJ 08854 USA.
-
- Sarkar, Tapati (author)
- Uppsala universitet,Fasta tillståndets fysik,Rutgers State Univ, Dept Chem & Chem Biol, 610 Taylor Rd, Piscataway, NJ 08854 USA.
-
- Abbett, Brian M. (author)
- Cornell Univ, Dept Appl & Engn Phys, Ithaca, NY 14853 USA.
-
- Pokorny, Jan (author)
- Acad Sci Czech Republic, Inst Phys, Na Slovance 2, Prague 18221 8, Czech Republic.
-
- Savinov, Maxim (author)
- Acad Sci Czech Republic, Inst Phys, Na Slovance 2, Prague 18221 8, Czech Republic.
-
- Nuzhnyy, Dmitry (author)
- Acad Sci Czech Republic, Inst Phys, Na Slovance 2, Prague 18221 8, Czech Republic.
-
- Prokleska, Jan (author)
- Charles Univ Prague, Fac Math & Phys, Dept Condensed Matter Phys, Ke Karlovu 5, CR-12116 Prague, Czech Republic.
-
- Abeykoon, Milinda (author)
- Brookhaven Natl Lab, Photon Sci Directorate, Upton, NY 11973 USA.
-
- Stephens, Peter W. (author)
- SUNY Stony Brook, Dept Phys & Astron, Stony Brook, NY 11794 USA.
-
- Hodges, Jason P. (author)
- Oak Ridge Natl Lab, Spallat Neutron Source, Oak Ridge, TN 37831 USA.
-
- Vanek, Premysl (author)
- Acad Sci Czech Republic, Inst Phys, Na Slovance 2, Prague 18221 8, Czech Republic.
-
- Fennie, Craig J. (author)
- Cornell Univ, Dept Appl & Engn Phys, Ithaca, NY 14853 USA.
-
- Rabe, Karin M. (author)
- Rutgers State Univ, Dept Phys & Astron, 136 Frelinghuysen Rd, Piscataway, NJ 08854 USA.
-
Kamba, Stanislav (author)
-
- Greenblatt, Martha (author)
- Rutgers State Univ, Dept Chem & Chem Biol, 610 Taylor Rd, Piscataway, NJ 08854 USA.
-
show less...
-
Rutgers State Univ, Dept Chem & Chem Biol, 610 Taylor Rd, Piscataway, NJ 08854 USA;CSIC, Inst Catalisis & Petr Quim, Grp Energia & Quim Sostenibles EQS, C Marie Curie 2,L10, Madrid 28049, Spain. Acad Sci Czech Republic, Inst Phys, Na Slovance 2, Prague 18221 8, Czech Republic. (creator_code:org_t)
- 2016-04-08
- 2016
- English.
-
In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 55:9, s. 4320-4329
- Related links:
-
https://www.bnl.gov/...
-
show more...
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- Pb2MnTeO6, a new double perovskite, was synthesized. Its crystal structure was determined by synchrotron X-ray and powder neutron diffraction. Pb2MnTeO6 is monoclinic (I2/m) at room temperature with a regular arrangement of all the cations in their polyhedra. However, when the temperature is lowered to similar to 120 K it undergoes a phase transition from I2/m to C2/c structure. This transition is accompanied by a displacement of the Pb atoms from the center of their polyhedra due to the 6s2 lone-pair electrons, together with a surprising off-centering of Mn2+ (d5) magnetic cations. This strong first-order phase transition is also evidenced by specific heat, dielectric, Raman, and infrared spectroscopy measurements. The magnetic characterizations indicate an anti-ferromagnetic (AFM) order below TN approximate to 20 K; analysis of powder neutron diffraction data confirms the magnetic structure with propagation vector k = (0 1 0) and collinear AFM spins. The observed jump in dielectric permittivity near similar to 150 K implies possible anti-ferroelectric behavior; however, the absence of switching suggests that Pb2MnTeO6 can only be antipolar. First-principle calculations confirmed that the crystal and magnetic structures determined are locally stable and that anti-ferroelectric switching is unlikely to be observed in Pb2MnTeO6.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database
- By the author/editor
-
Retuerto, Maria
-
Skiadopoulou, St ...
-
Li, Man-Rong
-
Abakumov, Artem ...
-
Croft, Mark
-
Ignatov, Alexand ...
-
show more...
-
Sarkar, Tapati
-
Abbett, Brian M.
-
Pokorny, Jan
-
Savinov, Maxim
-
Nuzhnyy, Dmitry
-
Prokleska, Jan
-
Abeykoon, Milind ...
-
Stephens, Peter ...
-
Hodges, Jason P.
-
Vanek, Premysl
-
Fennie, Craig J.
-
Rabe, Karin M.
-
Kamba, Stanislav
-
Greenblatt, Mart ...
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
-
and Inorganic Chemis ...
- Articles in the publication
-
Inorganic Chemis ...
- By the university
-
Uppsala University