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- Saadoune, IsmaelUniv Cadi Ayyad, Lab Chim Mat & Environm, Ave A Khattabi,BP 549, Marrakech, Morocco. (author)
Electrode Materials Based On Phosphates For Lithium Ion Batteries As An Efficient Energy Storage System
- Article/chapterEnglish2015
Publisher, publication year, extent ...
- 2015-07-31
- Hoboken, NJ, USA :WILEY-BLACKWELL,2015
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- LIBRIS-ID:oai:DiVA.org:uu-303215
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-303215URI
- https://doi.org/10.1002/9781119090427.ch36DOI
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- Language:English
- Summary in:English
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- Co0.5TiOPO4 and LiFe0.4Mn0.6PO4 phosphates present the electrochemical features of anode and cathode of lithium ion batteries, respectively. The cobalt oxyphosphate exhibits a high capacity and a working potential around 1.5 V. During the first discharge, an irreversible lithiation reaction occurs while during the subsequent cycles, a good reversibility of the charge/discharge process was obtained with a stable specific capacity approaching 280 mAh/g even at high rate. For the LiFe0.4Mn0.6PO4 olivine, the electrochemical process occurs in two steps involving separately two redox couples: Mn3+/Mn2+ and Fe3+/Fe2+. The electrochemical lithiation/delithiation occur without significant changes in the structure. Even if the obtained capacity ( 110 mAh/g), is lower that the theoretical one, the coulombic storage efficiency is rather good ( 95%).
Subject headings and genre
- TEKNIK OCH TEKNOLOGIER Materialteknik hsv//swe
- ENGINEERING AND TECHNOLOGY Materials Engineering hsv//eng
- Energy storage
- Li-ion Batteries
- Phosphates
Added entries (persons, corporate bodies, meetings, titles ...)
- Lasri, KarimaUniv Cadi Ayyad, Lab Chim Mat & Environm, Ave A Khattabi,BP 549, Marrakech, Morocco. (author)
- Bezza, IlhamUniv Cadi Ayyad, Lab Chim Mat & Environm, Ave A Khattabi,BP 549, Marrakech, Morocco.;KIT, IAM, D-76344 Eggenstein Leopoldshafen, Germany. (author)
- Indris, SylvioKIT, IAM, D-76344 Eggenstein Leopoldshafen, Germany. (author)
- Brandell, DanielUppsala universitet,Strukturkemi,Uppsala Univ, Dept Chem, Angstrom Lab, SE-75121 Uppsala, Sweden.(Swepub:uu)dbr10334 (author)
- Ehrenberg, HelmutKIT, IAM, D-76344 Eggenstein Leopoldshafen, Germany. (author)
- Univ Cadi Ayyad, Lab Chim Mat & Environm, Ave A Khattabi,BP 549, Marrakech, Morocco.Univ Cadi Ayyad, Lab Chim Mat & Environm, Ave A Khattabi,BP 549, Marrakech, Morocco.;KIT, IAM, D-76344 Eggenstein Leopoldshafen, Germany. (creator_code:org_t)
Related titles
- In:Proceedings of the TMS Middle East - Mediterranean Materials Congress on Energy and Infrastructure Systems (MEMA 2015)Hoboken, NJ, USA : WILEY-BLACKWELL, s. 343-34997811190904279781119065272
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