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Design and Control of Cooperativity in Spin-Crossover in Metal-Organic Complexes : A Theoretical Overview
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- Banerjee, Hrishit (author)
- SN Bose Natl Ctr Basic Sci, Dept Condensed Matter Phys & Mat Sci, JD Block,Sect 3, Kolkata 700106, India.
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- Chakraborty, Sudip (author)
- Uppsala universitet,Materialteori
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- Saha-Dasgupta, Tanusri (author)
- SN Bose Natl Ctr Basic Sci, Dept Condensed Matter Phys & Mat Sci, JD Block,Sect 3, Kolkata 700106, India.
- SN Bose Natl Ctr Basic Sci, Dept Condensed Matter Phys & Mat Sci, JD Block,Sect 3, Kolkata 700106, India Materialteori (creator_code:org_t)
- 2017-07-20
- 2017
- English.
- In: INORGANICS. - : MDPI AG. - 2304-6740. ; 5:3
- Research review (peer-reviewed)
Abstract
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- Metal organic complexes consisting of transition metal centers linked by organic ligands, may show bistability which enables the system to be observed in two different electronic states depending on external condition. One of the spectacular examples of molecular bistability is the spin-crossover phenomena. Spin-Crossover (SCO) describes the phenomena in which the transition metal ion in the complex under the influence of external stimuli may show a crossover between a low-spin and high-spin state. For applications in memory devices, it is desirable to make the SCO phenomena cooperative, which may happen with associated hysteresis effect. In this respect, compounds with extended solid state structures containing metal ions connected by organic spacer linkers like linear polymers, coordination network solids are preferred candidates over isolated molecules or molecular assemblies. The microscopic understanding, design and control of mechanism driving cooperativity, however, are challenging. In this review we discuss the recent theoretical progress in this direction.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Spin-Crossover (SCO)
- stimulus-induced spin transition
- crystal engineering of SCO and related complexes
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