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One-Pot Tandem Phot...
One-Pot Tandem Photoredox and Cross-Coupling Catalysis with a Single Palladium Carbodicarbene Complex
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- Hsu, Yu-Cheng (author)
- Acad Sinica, Inst Chem, Taipei 11529, Taiwan;Natl Taiwan Univ, Dept Chem, Taipei 10161, Taiwan
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- Wang, Vincent Cho-Chien (author)
- Uppsala universitet,Fysikalisk kemi,Acad Sinica, Inst Chem, Taipei 11529, Taiwan
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- Au-Yeung, Ka-Chun (author)
- Acad Sinica, Inst Chem, Taipei 11529, Taiwan
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- Tsai, Chung-Yu (author)
- Acad Sinica, Inst Chem, Taipei 11529, Taiwan
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- Chang, Chun-Chi (author)
- Acad Sinica, Inst Chem, Taipei 11529, Taiwan
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- Lin, Bo-Chao (author)
- Acad Sinica, Inst Chem, Taipei 11529, Taiwan
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- Chan, Yi-Tsu (author)
- Natl Taiwan Univ, Dept Chem, Taipei 10161, Taiwan
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- Hsu, Chao-Ping (author)
- Acad Sinica, Inst Chem, Taipei 11529, Taiwan
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- Yap, Glenn P. A. (author)
- Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA
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- Jurca, Titel (author)
- Univ Cent Florida, Dept Chem, Orlando, FL 32816 USA;Univ Cent Florida, Cluster Rational Design Catalysts Energy Applicat, Orlando, FL 32816 USA
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- Ong, Tiow-Gan (author)
- Acad Sinica, Inst Chem, Taipei 11529, Taiwan;Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 300, Taiwan
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(creator_code:org_t)
- 2018-03-13
- 2018
- English.
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In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 57:17, s. 4622-4626
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The combination of conventional transition-metal-catalyzed coupling (2e(-) process) and photoredox catalysis (1e(-) process) has emerged as a powerful approach to catalyze difficult cross-coupling reactions under mild reaction conditions. Reported is a palladium carbodicarbene (CDC) complex that mediates both a Suzuki-Miyaura coupling and photoredox catalysis for C-N bond formation upon visible-light irradiation. These two catalytic pathways can be combined to promote both conventional transition-metal-catalyzed coupling and photoredox catalysis to mediate C-H arylation under ambient conditions with a single catalyst in an efficient one-pot process.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- carbenes
- cross-coupling
- palladium
- photocatalysis
- reaction mechanisms
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Hsu, Yu-Cheng
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Wang, Vincent Ch ...
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Au-Yeung, Ka-Chu ...
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Tsai, Chung-Yu
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Chang, Chun-Chi
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Lin, Bo-Chao
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show more...
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Chan, Yi-Tsu
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Hsu, Chao-Ping
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Yap, Glenn P. A.
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Jurca, Titel
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Ong, Tiow-Gan
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Organic Chemistr ...
- Articles in the publication
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Angewandte Chemi ...
- By the university
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Uppsala University