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Formal water oxidat...
Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration
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- Bhunia, Asamanjoy (author)
- Uppsala universitet,Molekylär biomimetik,Natl Inst Technol Puducherry, Dept Chem, Karaikal 609609, India
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- Johnson, Ben A. (author)
- Uppsala universitet,Molekylär biomimetik
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- Czapla-Masztafiak, Joanna (author)
- Polish Acad Sci, Inst Nucl Phys, PL-31342 Krakow, Poland
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- Sá, Jacinto (author)
- Uppsala universitet,Fysikalisk kemi,Polish Acad Sci, Inst Phys Chem, Ul Kasprzaka 44-52, PL-01224 Warsaw, Poland
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- Ott, Sascha (author)
- Uppsala universitet,Molekylär biomimetik
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(creator_code:org_t)
- 2018
- 2018
- English.
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In: Chemical Communications. - : ROYAL SOC CHEMISTRY. - 1359-7345 .- 1364-548X. ; 54, s. 7770-7773
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Abstract
Subject headings
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- The molecular water oxidation catalyst [Ru(bda)(L)(2)] has been incorporated into pyridine-decorated MIL-101(Cr) metal-organic frameworks. The resulting MIL-101@Ru materials exhibit turnover frequencies (TOFs) up to ten times higher compared to the homogenous reference. An unusual dependence of the formal TOFs on oxidant concentration is observed that ultimately arises from differing amounts of catalysts in the MOF crystals being active.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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