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New Quadratic Self-...
New Quadratic Self-Assembly of Double-Decker Phthalocyanine on Gold(111) Surface : From Macroscopic to Microscopic Scale
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- Farronato, M. (author)
- Sorbonne Univ, CNRS, Inst Nanosci Paris, UMR 7588, 4 Pl Jussieu, F-75005 Paris, France
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- Bidermane, Ieva, 1984- (author)
- Uppsala universitet,Materialteori,Helmholtz Zentrum Berlin Bessy II, Inst Methods & Instrumentat Synchrotron Radiat Re, Albert Einstein Str 15, D-12489 Berlin, Germany
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- Lüder, Johann (author)
- Uppsala universitet,Materialteori,Natl Univ Singapore, Dept Mech Engn, Block EA 07-08,9 Engn Dr 1, Singapore 117576, Singapore
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- Bouvet, M. (author)
- Univ Bourgogne, CNRS, ICMUB, UMR 6302, F-21078 Dijon, France
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- Vlad, A. (author)
- Synchrotron SOLEIL, F-91192 Gif Sur Yvette, France
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- Jones, A. (author)
- Graz Univ Technol, Inst Solid State Phys, A-8010 Graz, Austria
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- Simbrunner, J. (author)
- Graz Univ Technol, Inst Solid State Phys, A-8010 Graz, Austria
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- Resel, R. (author)
- Graz Univ Technol, Inst Solid State Phys, A-8010 Graz, Austria
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- Brena, Barbara (author)
- Uppsala universitet,Materialteori
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- Prevot, G. (author)
- Sorbonne Univ, CNRS, Inst Nanosci Paris, UMR 7588, 4 Pl Jussieu, F-75005 Paris, France
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- Witkowski, N. (author)
- Sorbonne Univ, CNRS, Inst Nanosci Paris, UMR 7588, 4 Pl Jussieu, F-75005 Paris, France
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(creator_code:org_t)
- 2018-11-02
- 2018
- English.
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In: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 122:46, s. 26480-26488
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Unveiling the self-organization mechanism of semiconducting organic molecules onto metallic surfaces is the first step to design hybrid devices in which the self-assembling is exploited to tailor magnetic properties. In this study, double-decker rare-earth phthalocyanines, namely, lutetium phthalocyanine (LuPc2), are deposited on Au(111) gold surface forming large-scale self-assemblies. Global and local experimental techniques, namely, grazing incidence X-ray diffraction and scanning tunneling microscopy, supplemented by density functional theory calculations with van der Waals corrections, give insight into the molecular structural arrangement of the thin film and the self organization at the surface. Our results show unambiguously that the two plateaus of the double-decker phthalocyanine present a different rotation than the isolated molecule. This is evidenced by density functional theory simulations of optimized LuPc2 monolayer showing a perfect agreement with experimental findings. Moreover, the stabilized structure of double layers reveals an eclipsed configuration of the molecules in the stacking, having the ligand plateaus parallel to the gold surface. The high crystallinity of the molecular assembly and its weak electronic coupling with the metallic substrate is expected to open new perspective in magnetic devices.
Subject headings
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
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- ref (subject category)
- art (subject category)
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- By the author/editor
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Farronato, M.
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Bidermane, Ieva, ...
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Lüder, Johann
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Bouvet, M.
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Vlad, A.
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Jones, A.
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show more...
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Simbrunner, J.
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Resel, R.
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Brena, Barbara
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Prevot, G.
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Witkowski, N.
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Condensed Matter ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Physical Chemist ...
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The Journal of P ...
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Uppsala University