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2-azanorbornyl alcohols: Very efficient ligands for ruthenium-catalyzed asymmetric transfer hydrogenation of aromatic ketones
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- Alonso, DA (author)
- Uppsala universitet,Kemiska institutionen
- Nordin, SJM (author)
- Roth, P (author)
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- Tarnai, T (author)
- Andersson, PG (author)
- Thommen, M (author)
- Pittelkow, U (author)
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- (creator_code:org_t)
- AMER CHEMICAL SOC, 2000
- 2000
- English.
- In: JOURNAL OF ORGANIC CHEMISTRY. - : AMER CHEMICAL SOC. - 0022-3263. ; 65:10, s. 3116-3122
- Journal article (peer-reviewed)
Abstract
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- 2-Azanorbornyl-derived amino alcohols were prepared and evaluated as ligands in the Ru(II)-catalyzed asymmetric transfer hydrogenation of aromatic ketones. To improve selectivity and rate, the structure of the ligand was optimized, Acetophenone was reduce
Keyword
- ENANTIOSELECTIVE TRANSFER HYDROGENATION; HIGHLY EFFICIENT; CHIRAL LIGANDS; ALPHA;BETA-UNSATURATED KETONES; TRANSFER REDUCTION; CARBONYL-COMPOUNDS; ALLYLIC ALCOHOLS; SCHIFF-BASES; COMPLEXES; OXAZABOROLIDINES
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- Nordin, SJM
- Roth, P
- Tarnai, T
- Andersson, PG
- Thommen, M
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