Intramolecular amidomercurations under allylic control: a stereoselective synthesis of (+)-pseudohygroline and (+)-3-hydroxypyrrolizidine

• The diastereoselectivity of intramolecular amidomercurations can be reversed by altering the remote allylic substituent of omega -alkenylcarbamates. This methodology has been applied to the synthesis of (+)-pseudohygroline and (+)-3-hydroxypyrrolizidine.

Keyword

OXYMERCURATIONS; ALKALOIDS

Publication and Content Type

ref (subject category)

art (subject category)