Search: onr:"swepub:oai:DiVA.org:uu-379261" >
Synthesis of a mini...
Synthesis of a miniaturized [FeFe] hydrogenase model system
-
- Esmieu, Charlene (author)
- Uppsala universitet,Molekylär biomimetik,CNRS, LCC, 205 Route Narbonne,BP 44099, F-31077 Toulouse 4, France
-
- Guo, Meiyuan (author)
- Uppsala universitet,Teoretisk kemi
-
- Redman, Holly J. (author)
- Uppsala universitet,Molekylär biomimetik
-
show more...
-
- Lundberg, Marcus, 1974- (author)
- Uppsala universitet,Teoretisk kemi
-
- Berggren, Gustav (author)
- Uppsala universitet,Molekylär biomimetik
-
show less...
-
(creator_code:org_t)
- 2019
- 2019
- English.
-
In: Dalton Transactions. - : ROYAL SOC CHEMISTRY. - 1477-9226 .- 1477-9234. ; 48:7, s. 2280-2284
- Related links:
-
https://doi.org/10.1...
-
show more...
-
https://uu.diva-port... (primary) (Raw object)
-
https://pubs.rsc.org...
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- The reaction occurring during artificial maturation of [FeFe] hydrogenase has been recreated using molecular systems. The formation of a miniaturized [FeFe] hydrogenase model system, generated through the combination of a [4Fe4S] cluster binding oligopeptide and an organometallic Fe complex, has been monitored by a range of spectroscopic techniques. A structure of the final assembly is suggested based on EPR and FTIR spectroscopy in combination with DFT calculations. The capacity of this novel H-cluster model to catalyze H-2 production in aqueous media at mild potentials is verified in chemical assays.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database