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Synthesis of a mini...
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Esmieu, CharleneUppsala universitet,Molekylär biomimetik,CNRS, LCC, 205 Route Narbonne,BP 44099, F-31077 Toulouse 4, France
(author)
Synthesis of a miniaturized [FeFe] hydrogenase model system
- Article/chapterEnglish2019
Publisher, publication year, extent ...
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2019
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ROYAL SOC CHEMISTRY,2019
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electronicrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:uu-379261
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-379261URI
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https://doi.org/10.1039/c8dt05085fDOI
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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The reaction occurring during artificial maturation of [FeFe] hydrogenase has been recreated using molecular systems. The formation of a miniaturized [FeFe] hydrogenase model system, generated through the combination of a [4Fe4S] cluster binding oligopeptide and an organometallic Fe complex, has been monitored by a range of spectroscopic techniques. A structure of the final assembly is suggested based on EPR and FTIR spectroscopy in combination with DFT calculations. The capacity of this novel H-cluster model to catalyze H-2 production in aqueous media at mild potentials is verified in chemical assays.
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Guo, MeiyuanUppsala universitet,Teoretisk kemi(Swepub:uu)meigu662
(author)
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Redman, Holly J.Uppsala universitet,Molekylär biomimetik(Swepub:uu)holre224
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Lundberg, Marcus,1974-Uppsala universitet,Teoretisk kemi(Swepub:uu)marlu250
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Berggren, GustavUppsala universitet,Molekylär biomimetik(Swepub:uu)guber255
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Uppsala universitetMolekylär biomimetik
(creator_code:org_t)
Related titles
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In:Dalton Transactions: ROYAL SOC CHEMISTRY48:7, s. 2280-22841477-92261477-9234
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