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Efficient visible l...
Efficient visible light-driven water oxidation catalysed by an iron(IV) clathrochelate complex
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- Shylin, Sergii I. (author)
- Uppsala universitet,Fysikalisk kemi
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- Pavliuk, Mariia V. (author)
- Uppsala universitet,Fysikalisk kemi
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- D'Amario, Luca (author)
- Uppsala universitet,Fysikalisk kemi
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- Mamedov, Fikret, Ph.D., Dr.Sci. (author)
- Uppsala universitet,Molekylär biomimetik
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- Sá, Jacinto (author)
- Uppsala universitet,Fysikalisk kemi
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- Berggren, Gustav (author)
- Uppsala universitet,Molekylär biomimetik
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- Fritsky, Igor O. (author)
- Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska 64, 01601 Kiev, Ukraine
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(creator_code:org_t)
- 2019
- 2019
- English.
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In: Chemical Communications. - 1359-7345 .- 1364-548X. ; 55:23, s. 3335-3338
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https://doi.org/10.1...
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https://uu.diva-port... (primary) (Raw object)
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Abstract
Subject headings
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- A water-stable FeIV clathrochelate complex catalyzes fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s−1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Artificial photosynthesis
- water oxidation
- iron catalyst
- photochemical water oxidation
- electrochemical water oxidation
- Chemistry with specialization in Physical Chemistry
- Kemi med inriktning mot fysikalisk kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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