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Cadmium Free Cu2ZnSnS4 Solar Cells with 9.7% Efficiency

Larsen, Jes K (author)
Uppsala universitet,Fasta tillståndets elektronik
Larsson, Fredrik (author)
Uppsala universitet,Fasta tillståndets elektronik
Törndahl, Tobias, 1974- (author)
Uppsala universitet,Fasta tillståndets elektronik
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Saini, Nishant (author)
Uppsala universitet,Fasta tillståndets elektronik
Riekehr, Lars (author)
Uppsala universitet,Fasta tillståndets elektronik
Ren, Yi (author)
Uppsala universitet,Fasta tillståndets elektronik,Midsummer AB, Elect Hojden 6, S-17543 Jarfalla, Sweden
Biswal, Adyasha (author)
KIT, Inst Photon Sci & Synchrotron Radiat IPS, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany;KIT, Inst Chem Technol & Polymer Chem ITCP, Engesserstr 18-20, D-76128 Karlsruhe, Germany
Hauschild, Dirk (author)
KIT, Inst Photon Sci & Synchrotron Radiat IPS, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany;KIT, Inst Chem Technol & Polymer Chem ITCP, Engesserstr 18-20, D-76128 Karlsruhe, Germany
Weinhardt, Lothar (author)
KIT, Inst Photon Sci & Synchrotron Radiat IPS, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany;KIT, Inst Chem Technol & Polymer Chem ITCP, Engesserstr 18-20, D-76128 Karlsruhe, Germany;Univ Nevada, Dept Chem & Biochem, Las Vegas UNLV, 4505 Maryland Pkwy, Las Vegas, NV 89154 USA
Heske, Clemens (author)
KIT, Inst Photon Sci & Synchrotron Radiat IPS, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany;KIT, Inst Chem Technol & Polymer Chem ITCP, Engesserstr 18-20, D-76128 Karlsruhe, Germany;Univ Nevada, Dept Chem & Biochem, Las Vegas UNLV, 4505 Maryland Pkwy, Las Vegas, NV 89154 USA
Platzer Björkman, Charlotte, 1976- (author)
Uppsala universitet,Fasta tillståndets elektronik
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 (creator_code:org_t)
2019-04-16
2019
English.
In: Advanced Energy Materials. - : Wiley. - 1614-6832 .- 1614-6840. ; 9:21
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Cu2ZnSnS4(CZTS) thin-film solar cell absorbers with different bandgaps can be produced by parameter variation during thermal treatments. Here, the effects of varied annealing time in a sulfur atmosphere and an ordering treatment of the absorber are compared. Chemical changes in the surface due to ordering are examined, and a downshift of the valence band edge is observed. With the goal to obtain different band alignments, these CZTS absorbers are combined with Zn1−xSnxOy (ZTO) or CdS buffer layers to produce complete devices. A high open circuit voltage of 809 mV is obtained for an ordered CZTS absorber with CdS buffer layer, while a 9.7% device is obtained utilizing a Cd free ZTO buffer layer. The best performing devices are produced with a very rapid 1 min sulfurization, resulting in very small grains.

Subject headings

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

Keyword

Cu2ZnSnS4
thermal treatment
thin-film solar cells
valence bands

Publication and Content Type

ref (subject category)
art (subject category)

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