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Manganese Hexacyano...
Manganese Hexacyanomanganate as a Positive Electrode for Nonaqueous Li-, Na-, and K-Ion Batteries
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- Renman, Viktor (author)
- Uppsala universitet,Strukturkemi,Ångström Advanced Battery Centre
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- Ojwang, Dickson O. (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Stockholm Univ, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden
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- Gómez, Cesar Pay, Docent, 1974- (author)
- Uppsala universitet,Strukturkemi,Ångström Advanced Battery Centre
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- Gustafsson, Torbjörn, 1949- (author)
- Uppsala universitet,Strukturkemi,Ångström Advanced Battery Centre
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- Edström, Kristina, Professor, 1958- (author)
- Uppsala universitet,Strukturkemi,Ångström Advanced Battery Centre
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- Svensson, Gunnar (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Stockholm Univ, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden
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- Valvo, Mario (author)
- Uppsala universitet,Strukturkemi,Ångström Advanced Battery Centre
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(creator_code:org_t)
- 2019-08-26
- 2019
- English.
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In: The Journal of Physical Chemistry C. - : AMER CHEMICAL SOC. - 1932-7447 .- 1932-7455. ; 123:36, s. 22040-22049
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- K2Mn[Mn(CN)(6)] is synthesized, characterized, and evaluated as possible positive electrode material in nonaqueous Li-, Na-, and K-ion batteries. This compound belongs to the rich and versatile family of hexacyanometallates displaying distinctive structural properties, which makes it interesting for ion insertion purposes. It can be viewed as a perovskite-like compound in which CN-bridged Mn(CN)(6) octahedra form an open framework structure with sufficiently large diffusion channels able to accommodate a variety of insertion cations. By means of galvanostatic cycling and cyclic voltammetry tests in nonaqueous alkali metal half-cells, it is demonstrated that this material is able to reversibly host Li+, Na+, and K+ ions via electrochemical insertion/deinsertion within a wide voltage range. The general electrochemical features are similar for all of these three ion insertion chemistries. An in operando X-ray diffraction investigation indicates that the original monoclinic structure is transformed into a cubic one during charging (i.e., removal of cations from the host framework) and that such a process is reversible upon subsequent cell discharge and cation reuptake.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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