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- Gupta, Arvind KumarUppsala universitet,Syntetisk molekylär kemi (author)
Solvent and Counter-Ion Induced Coordination Environment Changes Towards Ag-I Coordination Polymers
- Article/chapterEnglish2019
Publisher, publication year, extent ...
- 2019-08-05
- WILEY-V C H VERLAG GMBH,2019
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:uu-396120
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-396120URI
- https://doi.org/10.1002/ejic.201900722DOI
Supplementary language notes
- Language:English
- Summary in:English
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- SwePubSwePub
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Notes
- A series of silver coordination polymers based on the 9,9 '-bis(4,5-diazafluorene) (BDF-H-2) ligand is presented. The choice of counterions and reaction conditions dictate the observed topology on the final systems by influencing the silver coordination environment. Coordination modes, flexibility of the ligand and extended pi-pi stacking interactions have allowed the preparation and crystallographic characterisation of one 1D- and three 2D-coordination polymers: 1D-[Ag(BDF-H-2)(DMSO)](n)(X)(n) (where X = OTf- and ClO4-); 1D-[Ag-2(BDF-H-2) m(1)-(TfO)(2),m(2)-(TfO)(2)](n)(TfO)(n), and 2D-[Ag-2(BDF-H-2)(3)](n)(PF6)(2n).
Subject headings and genre
- NATURVETENSKAP Kemi Oorganisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Inorganic Chemistry hsv//eng
- Coordination polymers
- Diazafluorenes
- Solvent effects
- Silver
- Topology
- polymers
Added entries (persons, corporate bodies, meetings, titles ...)
- Morales Salazar, DanielUppsala universitet,Syntetisk molekylär kemi(Swepub:uu)danmo207 (author)
- Orthaber, Andreas,1979-Uppsala universitet,Syntetisk molekylär kemi(Swepub:uu)ortan368 (author)
- Uppsala universitetSyntetisk molekylär kemi (creator_code:org_t)
Related titles
- In:European Journal of Inorganic Chemistry: WILEY-V C H VERLAG GMBH2019:33, s. 3740-37441434-19481099-19481099-0682
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