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Spin crossover in t...
Spin crossover in the Prussian blue analogue FePt(CN)(6 )induced by pressure or X-ray irradiation
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- Boström, Hanna L. B. (author)
- Uppsala universitet,Institutionen för kemi - Ångström
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- Cairns, Andrew B. (author)
- Imperial Coll London, Dept Mat, Royal Sch Mines, Exhibit Rd, London, England.
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- Liu, Lei (author)
- Uppsala universitet,Mineralogi, petrologi och tektonik
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- Lazor, Peter (author)
- Uppsala universitet,Mineralogi, petrologi och tektonik
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- Collings, Ines E. (author)
- Empa Swiss Fed Labs Mat Sci & Technol, Ctr Xray Analyt, Uberlandstr 129, CH-8600 Dubendorf, Switzerland.
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(creator_code:org_t)
- 2020
- 2020
- English.
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In: Dalton Transactions. - : ROYAL SOC CHEMISTRY. - 1477-9226 .- 1477-9234. ; 49:37, s. 12940-12944
- Related links:
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https://pubs.rsc.org...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The spin state of the Prussian blue analogue (FePtIV)-Pt-II (CN)(6) is investigated in response to temperature, pressure, and X-ray irradiation. White cooling to 10 K maintains the high-spin state of Fe-II, compression at ambient temperature induces a first-order spin-crossover (SCO) transition with a small hysteresis loop (p up arrow = 0.8 GPa, p down arrow= 0.6 GPa). In addition, the high-spin to low-spin transition can be initiated at lower pressure through increased X-ray irradiation. Our study highlights a cooperative SCO with moderate pressure in a porous Prussian blue analogue.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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