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Formation of High-P...
Formation of High-Performance Multi-Cation Halide Perovskites Photovoltaics by delta-CsPbI3/delta-RbPbI3 Seed-Assisted Heterogeneous Nucleation
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- Alharbi, Essa A. (author)
- Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Baumeler, Thomas P. (author)
- Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Krishna, Anurag (author)
- Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Alyamani, Ahmed Y. (author)
- Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
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- Eickemeyer, Felix T. (author)
- Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Ouellette, Olivier (author)
- Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Pan, Linfeng (author)
- Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Alghamdi, Fahad S. (author)
- Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
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- Wang, Zaiwei (author)
- Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Alotaibi, Mohammad Hayal (author)
- Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
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- Yang, Bowen (author)
- Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Almalki, Masaud (author)
- Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Mensi, Mounir D. (author)
- Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn ISIC, CH-1950 Sion, Switzerland.
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- Albrithen, Hamad (author)
- Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.;KA CARE Energy Res & Innovat Ctr Riyadh, Riyadh, Saudi Arabia.;King Saud Univ, Lab Appl Sensing Res, King Abdullah Inst Nanotechnol Aramco, Riyadh 11451, Saudi Arabia.;King Saud Univ, Coll Sci, Dept Phys & Astron, Res Chair Tribol Surface & Interface Sci, Riyadh 11451, Saudi Arabia.
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- Albadri, Abdulrahman (author)
- Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
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- Hagfeldt, Anders (author)
- Uppsala universitet,Fysikalisk kemi,Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Zakeeruddin, Shaik M. (author)
- Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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- Gratzel, Michael (author)
- Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland. (creator_code:org_t)
- 2021-03-15
- 2021
- English.
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In: Advanced Energy Materials. - : John Wiley & Sons. - 1614-6832 .- 1614-6840. ; 11:16
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The performance of perovskite solar cells is highly dependent on the fabrication method; thus, controlling the growth mechanism of perovskite crystals is a promising way towards increasing their efficiency and stability. Herein, a multi-cation halide composition of perovskite solar cells is engineered via the two-step sequential deposition method. Strikingly, it is found that adding mixtures of 1D polymorphs of orthorhombic delta-RbPbI3 and delta-CsPbI3 to the PbI2 precursor solution induces the formation of porous mesostructured hexagonal films. This porosity greatly facilitates the heterogeneous nucleation and the penetration of FA (formamidinium)/MA (methylammonium) cations within the PbI2 film. Thus, the subsequent conversion of PbI2 into the desired multication cubic alpha-structure by exposing it to a solution of formamidinium methylammonium halides is greatly enhanced. During the conversion step, the delta-CsPbI3 also is fully integrated into the 3D mixed cation perovskite lattice, which exhibits high crystallinity and superior optoelectronic properties. The champion device shows a power conversion efficiency (PCE) over 22%. Furthermore, these devices exhibit enhanced operational stability, with the best device retaining more than 90% of its initial value of PCE under 1 Sun illumination with maximum power point tracking for 400 h.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- compositional engineering
- Perovskite solar cells
- stability
- two step methods
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Alharbi, Essa A.
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Baumeler, Thomas ...
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Krishna, Anurag
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Alyamani, Ahmed ...
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Eickemeyer, Feli ...
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Ouellette, Olivi ...
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show more...
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Pan, Linfeng
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Alghamdi, Fahad ...
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Wang, Zaiwei
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Alotaibi, Mohamm ...
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Yang, Bowen
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Almalki, Masaud
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Mensi, Mounir D.
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Albrithen, Hamad
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Albadri, Abdulra ...
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Hagfeldt, Anders
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Zakeeruddin, Sha ...
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Gratzel, Michael
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Materials Chemis ...
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Advanced Energy ...
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Uppsala University