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Formation of High-Performance Multi-Cation Halide Perovskites Photovoltaics by delta-CsPbI3/delta-RbPbI3 Seed-Assisted Heterogeneous Nucleation

Alharbi, Essa A. (author)
Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Baumeler, Thomas P. (author)
Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Krishna, Anurag (author)
Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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Alyamani, Ahmed Y. (author)
Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
Eickemeyer, Felix T. (author)
Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Ouellette, Olivier (author)
Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Pan, Linfeng (author)
Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Alghamdi, Fahad S. (author)
Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
Wang, Zaiwei (author)
Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Alotaibi, Mohammad Hayal (author)
Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
Yang, Bowen (author)
Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Almalki, Masaud (author)
Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Mensi, Mounir D. (author)
Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn ISIC, CH-1950 Sion, Switzerland.
Albrithen, Hamad (author)
Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.;KA CARE Energy Res & Innovat Ctr Riyadh, Riyadh, Saudi Arabia.;King Saud Univ, Lab Appl Sensing Res, King Abdullah Inst Nanotechnol Aramco, Riyadh 11451, Saudi Arabia.;King Saud Univ, Coll Sci, Dept Phys & Astron, Res Chair Tribol Surface & Interface Sci, Riyadh 11451, Saudi Arabia.
Albadri, Abdulrahman (author)
Natl Ctr Nanotechnol King Abdulaziz City Sci & Te, Riyadh 11442, Saudi Arabia.
Hagfeldt, Anders (author)
Uppsala universitet,Fysikalisk kemi,Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Zakeeruddin, Shaik M. (author)
Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
Gratzel, Michael (author)
Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland.
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Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland. (creator_code:org_t)
2021-03-15
2021
English.
In: Advanced Energy Materials. - : John Wiley & Sons. - 1614-6832 .- 1614-6840. ; 11:16
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The performance of perovskite solar cells is highly dependent on the fabrication method; thus, controlling the growth mechanism of perovskite crystals is a promising way towards increasing their efficiency and stability. Herein, a multi-cation halide composition of perovskite solar cells is engineered via the two-step sequential deposition method. Strikingly, it is found that adding mixtures of 1D polymorphs of orthorhombic delta-RbPbI3 and delta-CsPbI3 to the PbI2 precursor solution induces the formation of porous mesostructured hexagonal films. This porosity greatly facilitates the heterogeneous nucleation and the penetration of FA (formamidinium)/MA (methylammonium) cations within the PbI2 film. Thus, the subsequent conversion of PbI2 into the desired multication cubic alpha-structure by exposing it to a solution of formamidinium methylammonium halides is greatly enhanced. During the conversion step, the delta-CsPbI3 also is fully integrated into the 3D mixed cation perovskite lattice, which exhibits high crystallinity and superior optoelectronic properties. The champion device shows a power conversion efficiency (PCE) over 22%. Furthermore, these devices exhibit enhanced operational stability, with the best device retaining more than 90% of its initial value of PCE under 1 Sun illumination with maximum power point tracking for 400 h.

Subject headings

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

Keyword

compositional engineering
Perovskite solar cells
stability
two step methods

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ref (subject category)
art (subject category)

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