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Ternary Ionogel Ele...
Ternary Ionogel Electrolytes Enable Quasi-Solid-State Potassium Dual-Ion Intercalation Batteries
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- Kotronia, Antonia (author)
- Uppsala universitet,Strukturkemi
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- Edström, Kristina, Professor, 1958- (author)
- Uppsala universitet,Strukturkemi
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- Brandell, Daniel, 1975- (author)
- Uppsala universitet,Strukturkemi
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- Asfaw, Habtom Desta, Dr. 1986- (author)
- Uppsala universitet,Strukturkemi
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(creator_code:org_t)
- 2021-10-08
- 2022
- English.
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In: Advanced Energy and Sustainability Research. - : John Wiley & Sons. - 2699-9412. ; 3:1, s. 2100122-
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Abstract
Subject headings
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- A dual-ion battery (DIB) is an emerging technology destined for use in stationary energy storage applications. Most DIB prototypes use expensive salt-concentrated liquid electrolytes to ensure sufficient ion supply and an electrochemical stability window beyond 4.5 V, which is required for anion intercalation in graphite. Herein, the design of a compact quasi-solid-state potassium-based DIB is introduced using ternary ionogel electrolytes (t-IGEs) prepared from a potassium salt, an ionic liquid, and a poly(ionic liquid). Among a series of combinations, the t-IGE with optimum mechanical property, thermal stability (>200 °C), and electrochemical performance consists of 30% salt, 28% ionic liquid, and 42% poly(ionic liquid). With ionic conductivity ranging from 0.1 to 1 mS cm−1 at 30–100°C and an electrochemical stability window within 0.5–5.0 V versus K+/K, the t-IGE is suited for practical MoS2–graphite KDIBs. Infusing the ionogel in plain-weave glass fiber fabrics (≈40 μm thick) further enables the design of more compact KDIBs in which a significant reduction (≈64%) in electrolyte thickness is achieved. The cells are able to deliver specific capacities varying from 80 to 25 mAh g−1 at 10 to 160 mA g−1, with CEs ranging from ≈90% to 100%.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- dual-ion batteries
- graphite
- ionogel electrolyte
- s potassium
- transition metal dichalcogenide
Publication and Content Type
- ref (subject category)
- art (subject category)
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