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Two-dimensional correlation analysis for x-ray photoelectron spectroscopy

Li, S. (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA.
Driver, T. (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA.;Stanford PULSE Inst, Menlo Pk, CA 94025 USA.;SLAC Natl Accelerator Lab, Linac Coherent Light Source, 2575 Sand Hill Rd, Menlo Pk, CA 94025 USA.
Al Haddad, A. (author)
Paul Scherrer Inst, CH-5232 Villigen, Switzerland.;Argonne Natl Lab, Chem Sci & Engn Div, 9700 S Cass Ave, Argonne, IL 60439 USA.
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Champenois, E. G. (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA.;Stanford PULSE Inst, Menlo Pk, CA 94025 USA.
Agåker, Marcus (author)
Uppsala universitet,Institutionen för fysik och astronomi,Max IV Lab, Fotongatan 2, S-22484 Lund, Sweden.
Alexander, O. (author)
Imperial Coll London, Blackett Lab Extreme Light Consortium, London SW7 2AZ, England.
Barillot, T. (author)
Ecole Polytech Fed Lausanne, LUXS Lab Ultrafast Spect, Route Cantonale, CH-1015 Lausanne, Switzerland.
Bostedt, C. (author)
Paul Scherrer Inst, CH-5232 Villigen, Switzerland.;Argonne Natl Lab, Chem Sci & Engn Div, 9700 S Cass Ave, Argonne, IL 60439 USA.;Ecole Polytech Fed Lausanne, LUXS Lab Ultrafast Spect, Route Cantonale, CH-1015 Lausanne, Switzerland.
Garratt, D. (author)
Imperial Coll London, Blackett Lab Extreme Light Consortium, London SW7 2AZ, England.
Kjellsson, Ludvig (author)
Uppsala universitet,Institutionen för fysik och astronomi
Lutman, A. A. (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA.
Rubensson, Jan-Erik (author)
Uppsala universitet,Institutionen för fysik och astronomi
Sathe, C. (author)
Max IV Lab, Fotongatan 2, S-22484 Lund, Sweden.
Marinelli, A. (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA.
Marangos, J. P. (author)
Imperial Coll London, Blackett Lab Extreme Light Consortium, London SW7 2AZ, England.
Cryan, J. P. (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA.;Stanford PULSE Inst, Menlo Pk, CA 94025 USA.;SLAC Natl Accelerator Lab, Linac Coherent Light Source, 2575 Sand Hill Rd, Menlo Pk, CA 94025 USA.
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SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA SLAC Natl Accelerator Lab, Menlo Pk, CA 94205 USA.;Stanford PULSE Inst, Menlo Pk, CA 94025 USA.;SLAC Natl Accelerator Lab, Linac Coherent Light Source, 2575 Sand Hill Rd, Menlo Pk, CA 94025 USA. (creator_code:org_t)
2021-08-12
2021
English.
In: Journal of Physics B. - : Institute of Physics Publishing (IOPP). - 0953-4075 .- 1361-6455. ; 54:14
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • X-ray photoelectron spectroscopy (XPS) measures the binding energy of core-level electrons, which are well-localised to specific atomic sites in a molecular system, providing valuable information on the local chemical environment. The technique relies on measuring the photoelectron spectrum upon x-ray photoionisation, and the resolution is often limited by the bandwidth of the ionising x-ray pulse. This is particularly problematic for time-resolved XPS, where the desired time resolution enforces a fundamental lower limit on the bandwidth of the x-ray source. In this work, we report a novel correlation analysis which exploits the correlation between the x-ray and photoelectron spectra to improve the resolution of XPS measurements. We show that with this correlation-based spectral-domain ghost imaging method we can achieve sub-bandwidth resolution in XPS measurements. This analysis method enables XPS for sources with large bandwidth or spectral jitter, previously considered unfeasible for XPS measurements.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

x-ray photoelectron spectroscopy
free-electron laser
ghost imaging
AMO physics

Publication and Content Type

ref (subject category)
art (subject category)

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