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Ag Surface and Bulk Segregations in Sputtered ZrCuAlNi Metallic Glass Thin Films

Steinhoff, Michael K. (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.;Fraunhofer Inst Laser Technol ILT, Steinbachstr 15, D-52074 Aachen, Germany.
Holzapfel, Damian M. (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.
Karimi Aghda, Soheil (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.
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Neuss, Deborah (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.
Pöllmann, Peter J. (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.
Hans, Marcus (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.
Primetzhofer, Daniel (author)
Uppsala universitet,Tillämpad kärnfysik
Schneider, Jochen M. (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.
Azina, Clio (author)
Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany.
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Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany;Fraunhofer Inst Laser Technol ILT, Steinbachstr 15, D-52074 Aachen, Germany. Rhein Westfal TH Aachen, Mat Chem, Kopernikusstr 10, D-52074 Aachen, Germany. (creator_code:org_t)
2022-02-22
2022
English.
In: Materials. - : MDPI AG. - 1996-1944. ; 15:5
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We report on the formation of Ag-containing ZrCuAlNi thin film metallic glass (nano)composites by a hybrid direct-current magnetron sputtering and high-power pulsed magnetron sputtering process. The effects of Ag content, substrate temperature and substrate bias potential on the phase formation and morphology of the nanocomposites were investigated. While applying a substrate bias potential did not strongly affect the morphological evolution of the films, the Ag content dictated the size and distribution of Ag surface segregations. The films deposited at low temperatures were characterized by strong surface segregations, formed by coalescence and Ostwald ripening, while the volume of the films remained featureless. At higher deposition temperature, elongated Ag segregations were observed in the bulk and a continuous Ag layer was formed at the surface as a result of thermally enhanced surface diffusion. While microstructural observations have allowed identifying both surface and bulk segregations, an indirect method for detecting the presence of Ag segregations is proposed, by measuring the electrical resistivity of the films.

Subject headings

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

Keyword

thin film metallic glass
nanocomposites
segregation
electrical resistivity

Publication and Content Type

ref (subject category)
art (subject category)

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