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Four‐Step Spin Cros...
Four‐Step Spin Crossover in a New Cyano‐Bridged Iron‐Silver Coordination Polymer
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- Kucheriv, Olesia I. (author)
- Department of Chemistry Taras Shevchenko National University of Kyiv Volodymyrska St. 64 Kyiv 01601 Ukraine
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- Shylin, Sergii I. (author)
- Uppsala universitet,Molekylär biomimetik,Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University of Mainz, Staudingerweg 9, Mainz, 55099 Germany
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- Sirenko, Valerii Y. (author)
- Department of Chemistry Taras Shevchenko National University of Kyiv Volodymyrska St. 64 Kyiv 01601 Ukraine
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- Ksenofontov, Vadim (author)
- Institute of Inorganic and Analytical Chemistry Johannes Gutenberg University of Mainz Staudingerweg 9 Mainz 55099 Germany
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- Tremel, Wolfgang (author)
- Institute of Inorganic and Analytical Chemistry Johannes Gutenberg University of Mainz Staudingerweg 9 Mainz 55099 Germany
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- Dascălu, Ioan‐Andrei (author)
- Department of Inorganic Polymers Institute of Macromolecular Chemistry “Petru Poni” Aleea Grigore Ghica Voda 41 A Iasi 700487 Romania
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- Shova, Sergiu (author)
- Department of Inorganic Polymers Institute of Macromolecular Chemistry “Petru Poni” Aleea Grigore Ghica Voda 41 A Iasi 700487 Romania
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- Gural'skiy, Il'ya A. (author)
- Department of Chemistry Taras Shevchenko National University of Kyiv Volodymyrska St. 64 Kyiv 01601 Ukraine
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Department of Chemistry Taras Shevchenko National University of Kyiv Volodymyrska St 64 Kyiv 01601 Ukraine Molekylär biomimetik (creator_code:org_t)
- 2022-06-16
- 2022
- English.
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In: Chemistry - A European Journal. - : John Wiley & Sons. - 0947-6539 .- 1521-3765. ; 28:44
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A new guest-free Hofmann clathrate analogue Fe(2-ethoxypyrazine)2{Ag(CN)2}2 which undergoes a four-step spin crossover during the transition from the low-spin to the high-spin state is reported. At the first step 1/3 of centers become high spin, at the second step another 1/3 of centres become high spin, at the third step spin mixed crystallographic centres are observed, and after the fourth step all centers are high spin.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Spin transition
- spin crossover
- iron
- magnetism
- spin state
- Kemi med inriktning mot oorganisk kemi
- Chemistry with specialization in Inorganic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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