High turnover photocatalytic hydrogen formation with an Fe(iii) N-heterocyclic carbene photosensitiser

• Herein we report the first high turnover photocatalytic hydrogen formation reaction based on an earth-abundant Fe-III-NHC photosensitiser. The reaction occurs via reductive quenching of the (LMCT)-L-2 excited state that can be directly excited with green light and employs either Pt-colloids or [Co(dmgH)(2)pyCl] as proton reduction catalysts and [HNEt3][BF4] and triethanolamine/triethylamine as proton and electron donors. The outstanding photostability of the Fe-III-NHC complex enables turnover numbers >1000 without degradation.

Subject headings

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)

NATURVETENSKAP  -- Kemi -- Teoretisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)

NATURVETENSKAP  -- Kemi -- Organisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Organic Chemistry (hsv//eng)

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ref (subject category)

art (subject category)