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Carbanion Ruthenium Complexes for Water Oxidation

Howe, Andrew, 1995- (author)
Uppsala universitet,Syntetisk molekylär kemi,Uppsala University,Sascha Ott
Gil-Sepulcre, Marcos (author)
Institut Català d'Investigació Química - ICIQ,Llobet
Gimbert-Suriñach, Carolina (author)
Universitat Autònoma de Barcelona (UAB),Llobet
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Dooshaye, Moonshiram (author)
Instituto de Ciencia de Materiales de Madrid
Thapper, Anders, 1972- (author)
Uppsala universitet,Syntetisk molekylär kemi,Anders Thapper
Bousquet, Antoine (author)
Université de Pau et des Pays de l'Adour (UPPA)
Billon, Laurent (author)
Université de Pau et des Pays de l'Adour (UPPA),Laurent Billon
Ott, Sascha, 1973- (author)
Uppsala universitet,Syntetisk molekylär kemi,Sascha Ott
Llobet, Antoni, 1960- (author)
Institut Català d'Investigació Química - ICIQ,Llobet
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 (creator_code:org_t)
English.
  • Other publication (other academic/artistic)
Abstract Subject headings
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  • A novel carbanion complex, [RuIII(dpa)(4,4’-bypridine)2], (dpa = ((5-methyl-1,3-phenylene)bis(pyridine-6,2-diyl))bis(hydroxy(l1-oxidaneyl)phosphine oxide),), has been prepared, characterised and incorporated as a coordination oligomer to form II@MWCNT@GC. Once incorporated in a coordination oligomer, this otherwise inert and stable diphosphonate complex has the ability to engage in electrocatalysis, with Faradaic efficiency (FE) of up to 85%. Scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy and XPS was used to confirm anchoring onto the graphitic surface.

Subject headings

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Keyword

Chemistry with specialization in Inorganic Chemistry
Kemi med inriktning mot oorganisk kemi

Publication and Content Type

vet (subject category)
ovr (subject category)

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