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Carbonyl-Containing...
Carbonyl-Containing Solid Polymer Electrolyte Host Materials : Conduction and Coordination in Polyketone, Polyester, and Polycarbonate Systems
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- Eriksson, Therese, 1992- (author)
- Uppsala universitet,Strukturkemi
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- Gudla, Harish (author)
- Uppsala universitet,Strukturkemi
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- Manabe, Yumehiro (author)
- Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Kita 13 Nishi 8 Kita-ku, Sapporo, Hokkaido060-8628, Japan
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- Yoneda, Tomoki (author)
- Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Kita 13 Nishi 8 Kita-ku, Sapporo, Hokkaido060-8628, Japan
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- Friesen, Daniel (author)
- Uppsala universitet,Strukturkemi
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- Zhang, Chao (author)
- Uppsala universitet,Strukturkemi
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- Inokuma, Yasuhide (author)
- Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Kita 13 Nishi 8 Kita-ku, Sapporo, Hokkaido060-8628, Japan
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- Brandell, Daniel, 1975- (author)
- Uppsala universitet,Strukturkemi
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- Mindemark, Jonas (author)
- Uppsala universitet,Strukturkemi
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(creator_code:org_t)
- 2022-12-07
- 2022
- English.
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In: Macromolecules. - : American Chemical Society (ACS). - 0024-9297 .- 1520-5835. ; 55:24, s. 10940-10949
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https://uu.diva-port... (primary) (Raw object)
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Abstract
Subject headings
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- Research on solid polymer electrolytes (SPEs) is now moving beyond the realm of polyethers that have dominated the field for several decades. A promising alternative group of candidates for SPE host materials is carbonyl-containing polymers. In this work, SPE properties of three different types of carbonyl-coordinating polymers are compared: polycarbonates, polyesters, and polyketones. The investigated polymers were chosen to be as structurally similar as possible, with only the functional group being different, thereby giving direct insights into the role of the noncoordinating main-chain oxygens. As revealed by experimental measurements as well as molecular dynamics simulations, the polyketone possesses the lowest glass transition temperature, but the ion transport is limited by a high degree of crystallinity. The polycarbonate, on the other hand, displays a relatively low coordination strength but is instead limited by its low molecular flexibility. The polyester performs generally as an intermediate between the other two, which is reasonable when considering its structural relation to the alternatives. This work demonstrates that local changes in the coordinating environment of carbonyl-containing polymers can have a large effect on the overall ion conduction, thereby also showing that desired transport properties can be achieved by fine-tuning the polymer chemistry of carbonyl-containing systems.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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