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Efficient SF6 captu...
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Åhlén, MichelleUppsala universitet,Nanoteknologi och funktionella material
(author)
Efficient SF6 capture and separation in robust gallium- and vanadium-based metal–organic frameworks
- Article/chapterEnglish2023
Publisher, publication year, extent ...
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Royal Society of Chemistry,2023
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electronicrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:uu-517993
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-517993URI
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https://doi.org/10.1039/d3ta05297dDOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Sulfur hexafluoride (SF6) is a highly potent greenhouse gas (GHG) that is mainly emitted from high-voltage electrical applications. The global warming potential (GWP) of the gas is almost 23 000 times that of CO2 and therefore, controlling its emission and recovery is of great importance from both an environmental and economic perspective. Solid adsorbents and adsorption-based technology is a cost-effective and energy-efficient pathway to recapture SF6 from its sources, which usually consist of dilute SF6 in N2. Here, we present a group of four highly porous and robust gallium- or vanadium-based metal–organic frameworks (MOFs) with exceptional SF6 uptake and selectivity. In particular, the novel gallium 1,2,4,5-tetrakis(4-carboxlatephenyl)benzene (TCPB4−) MOF (Ga-TBAPy) possesses 1-dimensional channels of suitable size (5.2 × 8.4 Å and 5.3 × 10 Å) to adsorb up to 2.25 mmol g−1 of SF6 at 10 kPa with an excellent SF6-over-N2 selectivity of 418. Ga-TCPB also exhibits high chemical stability in aqueous and acidic media as well as in organic solvents. 3D electron diffraction (3D ED) patterns combined with high-resolution electron microscopy images were employed to investigate the structure of these water-stable and cyclable MOF SF6 adsorbents. Furthermore, this study demonstrates the possibility of using these highly stable MOFs to capture SF6 from a gas mixture as well as how MOFs can offer an alternative and efficient way to mitigate the global warming contributions from the emission of SF6.
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Zhou, YiCentre for High-resolution Electron Microscopy (CℏEM), School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, People's Republic of China;Shanghai Key Laboratory of High-resolution Electron Microscopy, ShanghaiTech University, Shanghai 201210, People's Republic of China
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Hedbom, Daniel,1983-Uppsala universitet,Nanoteknologi och funktionella material(Swepub:uu)danhe607
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Cho, Hae SungCentre for High-resolution Electron Microscopy (CℏEM), School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, People's Republic of China;Shanghai Key Laboratory of High-resolution Electron Microscopy, ShanghaiTech University, Shanghai 201210, People's Republic of China;Department of Chemistry, Chung-Ang University, Seoul, 06974, Republic of Korea
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Strømme, Maria,1970-Uppsala universitet,Nanoteknologi och funktionella material(Swepub:uu)mst26208
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Terasaki, OsamuCentre for High-resolution Electron Microscopy (CℏEM), School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, People's Republic of China;Shanghai Key Laboratory of High-resolution Electron Microscopy, ShanghaiTech University, Shanghai 201210, People's Republic of China
(author)
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Cheung, OceanUppsala universitet,Nanoteknologi och funktionella material(Swepub:uu)ocech274
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Uppsala universitetNanoteknologi och funktionella material
(creator_code:org_t)
Related titles
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In:Journal of Materials Chemistry A: Royal Society of Chemistry11:48, s. 26435-264412050-74882050-7496
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