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Tracking Cavity For...
Tracking Cavity Formation in Electron Solvation : Insights from X-ray Spectroscopy and Theory
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- Sopena Moros, Arturo (author)
- Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.
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- Li, Shuai (author)
- Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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- Li, Kai (author)
- Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.;Univ Chicago, Dept Phys, Chicago, IL 60637 USA.;Univ Chicago, James Franck Inst, Chicago, IL 60637 USA.
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- Doumy, Gilles (author)
- Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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- Southworth, Stephen H. (author)
- Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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- Otolski, Christopher (author)
- Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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- Schaller, Richard D. (author)
- Argonne Natl Lab, Ctr Nanoscale Mat, Lemont, IL 60439 USA.;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA.
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- Kumagai, Yoshiaki (author)
- Tokyo Univ Agr & Technol, Dept Appl Phys, Tokyo 1848588, Japan.
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- Rubensson, Jan-Erik (author)
- Uppsala universitet,Kemisk och biomolekylär fysik
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- Simon, Marc (author)
- Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, LCPMR, F-75005 Paris, France.
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- Dakovski, Georgi (author)
- SLAC, LCLS, Menlo Pk, CA 94025 USA.
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- Kunnus, Kristjan (author)
- SLAC, LCLS, Menlo Pk, CA 94025 USA.
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- Robinson, Joseph S. (author)
- SLAC, LCLS, Menlo Pk, CA 94025 USA.
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- Hampton, Christina Y. (author)
- SLAC, LCLS, Menlo Pk, CA 94025 USA.
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- Hoffman, David J. (author)
- SLAC, LCLS, Menlo Pk, CA 94025 USA.
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- Koralek, Jake (author)
- SLAC, LCLS, Menlo Pk, CA 94025 USA.
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- Loh, Zhi-Heng (author)
- Nanyang Technol Univ, Sch Chem Chem Engn & Biotechnol, Singapore 637371, Singapore.;Nanyang Technol Univ, Sch Phys & Math Sci, Singapore 637371, Singapore.
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- Santra, Robin (author)
- Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.;Univ Hamburg, Dept Phys, D-22607 Hamburg, Germany.
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- Inhester, Ludger (author)
- Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.
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- Young, Linda (author)
- Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.;Univ Chicago, Dept Phys, Chicago, IL 60637 USA.;Univ Chicago, James Franck Inst, Chicago, IL 60637 USA.
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Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA. (creator_code:org_t)
- American Chemical Society (ACS), 2024
- 2024
- English.
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 146:5, s. 3262-3269
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Abstract
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- We present time-resolved X-ray absorption spectra of ionized liquid water and demonstrate that OH radicals, H3O+ ions, and solvated electrons all leave distinct X-ray-spectroscopic signatures. Particularly, this allows us to characterize the electron solvation process through a tool that focuses on the electronic response of oxygen atoms in the immediate vicinity of a solvated electron. Our experimental results, supported by ab initio calculations, confirm the formation of a cavity in which the solvated electron is trapped. We show that the solvation dynamics are governed by the magnitude of the random structural fluctuations present in water. As a consequence, the solvation time is highly sensitive to temperature and to the specific way the electron is injected into water.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Sopena Moros, Ar ...
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Li, Shuai
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Li, Kai
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Doumy, Gilles
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Southworth, Step ...
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Otolski, Christo ...
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Schaller, Richar ...
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Kumagai, Yoshiak ...
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Rubensson, Jan-E ...
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Simon, Marc
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Dakovski, Georgi
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Kunnus, Kristjan
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Robinson, Joseph ...
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Hampton, Christi ...
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Hoffman, David J ...
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Koralek, Jake
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Loh, Zhi-Heng
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Santra, Robin
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Inhester, Ludger
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Young, Linda
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Atom and Molecul ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Theoretical Chem ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Condensed Matter ...
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Journal of the A ...
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Uppsala University