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Tracking Cavity For...
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Sopena Moros, ArturoDeutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.
(author)
Tracking Cavity Formation in Electron Solvation : Insights from X-ray Spectroscopy and Theory
- Article/chapterEnglish2024
Publisher, publication year, extent ...
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American Chemical Society (ACS),2024
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Numbers
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LIBRIS-ID:oai:DiVA.org:uu-523920
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-523920URI
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https://doi.org/10.1021/jacs.3c11857DOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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We present time-resolved X-ray absorption spectra of ionized liquid water and demonstrate that OH radicals, H3O+ ions, and solvated electrons all leave distinct X-ray-spectroscopic signatures. Particularly, this allows us to characterize the electron solvation process through a tool that focuses on the electronic response of oxygen atoms in the immediate vicinity of a solvated electron. Our experimental results, supported by ab initio calculations, confirm the formation of a cavity in which the solvated electron is trapped. We show that the solvation dynamics are governed by the magnitude of the random structural fluctuations present in water. As a consequence, the solvation time is highly sensitive to temperature and to the specific way the electron is injected into water.
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Li, ShuaiArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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Li, KaiArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.;Univ Chicago, Dept Phys, Chicago, IL 60637 USA.;Univ Chicago, James Franck Inst, Chicago, IL 60637 USA.
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Doumy, GillesArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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Southworth, Stephen H.Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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Otolski, ChristopherArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
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Schaller, Richard D.Argonne Natl Lab, Ctr Nanoscale Mat, Lemont, IL 60439 USA.;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA.
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Kumagai, YoshiakiTokyo Univ Agr & Technol, Dept Appl Phys, Tokyo 1848588, Japan.
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Rubensson, Jan-ErikUppsala universitet,Kemisk och biomolekylär fysik(Swepub:uu)janerube
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Simon, MarcSorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, LCPMR, F-75005 Paris, France.
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Dakovski, GeorgiSLAC, LCLS, Menlo Pk, CA 94025 USA.
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Kunnus, KristjanSLAC, LCLS, Menlo Pk, CA 94025 USA.
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Robinson, Joseph S.SLAC, LCLS, Menlo Pk, CA 94025 USA.
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Hampton, Christina Y.SLAC, LCLS, Menlo Pk, CA 94025 USA.
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Hoffman, David J.SLAC, LCLS, Menlo Pk, CA 94025 USA.
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Koralek, JakeSLAC, LCLS, Menlo Pk, CA 94025 USA.
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Loh, Zhi-HengNanyang Technol Univ, Sch Chem Chem Engn & Biotechnol, Singapore 637371, Singapore.;Nanyang Technol Univ, Sch Phys & Math Sci, Singapore 637371, Singapore.
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Santra, RobinDeutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.;Univ Hamburg, Dept Phys, D-22607 Hamburg, Germany.
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Inhester, LudgerDeutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.
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Young, LindaArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.;Univ Chicago, Dept Phys, Chicago, IL 60637 USA.;Univ Chicago, James Franck Inst, Chicago, IL 60637 USA.
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Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.
(creator_code:org_t)
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In:Journal of the American Chemical Society: American Chemical Society (ACS)146:5, s. 3262-32690002-78631520-5126
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Sopena Moros, Ar ...
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Li, Shuai
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Li, Kai
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Doumy, Gilles
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Southworth, Step ...
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Otolski, Christo ...
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Schaller, Richar ...
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Kumagai, Yoshiak ...
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Rubensson, Jan-E ...
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Simon, Marc
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Dakovski, Georgi
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Kunnus, Kristjan
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Robinson, Joseph ...
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Hampton, Christi ...
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Hoffman, David J ...
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Koralek, Jake
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Loh, Zhi-Heng
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Santra, Robin
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Inhester, Ludger
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Young, Linda
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