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  • Sopena Moros, ArturoDeutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany. (author)

Tracking Cavity Formation in Electron Solvation : Insights from X-ray Spectroscopy and Theory

  • Article/chapterEnglish2024

Publisher, publication year, extent ...

  • American Chemical Society (ACS),2024
  • electronicrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:uu-523920
  • https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-523920URI
  • https://doi.org/10.1021/jacs.3c11857DOI

Supplementary language notes

  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • We present time-resolved X-ray absorption spectra of ionized liquid water and demonstrate that OH radicals, H3O+ ions, and solvated electrons all leave distinct X-ray-spectroscopic signatures. Particularly, this allows us to characterize the electron solvation process through a tool that focuses on the electronic response of oxygen atoms in the immediate vicinity of a solvated electron. Our experimental results, supported by ab initio calculations, confirm the formation of a cavity in which the solvated electron is trapped. We show that the solvation dynamics are governed by the magnitude of the random structural fluctuations present in water. As a consequence, the solvation time is highly sensitive to temperature and to the specific way the electron is injected into water.

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  • Li, ShuaiArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA. (author)
  • Li, KaiArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.;Univ Chicago, Dept Phys, Chicago, IL 60637 USA.;Univ Chicago, James Franck Inst, Chicago, IL 60637 USA. (author)
  • Doumy, GillesArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA. (author)
  • Southworth, Stephen H.Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA. (author)
  • Otolski, ChristopherArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA. (author)
  • Schaller, Richard D.Argonne Natl Lab, Ctr Nanoscale Mat, Lemont, IL 60439 USA.;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA. (author)
  • Kumagai, YoshiakiTokyo Univ Agr & Technol, Dept Appl Phys, Tokyo 1848588, Japan. (author)
  • Rubensson, Jan-ErikUppsala universitet,Kemisk och biomolekylär fysik(Swepub:uu)janerube (author)
  • Simon, MarcSorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, LCPMR, F-75005 Paris, France. (author)
  • Dakovski, GeorgiSLAC, LCLS, Menlo Pk, CA 94025 USA. (author)
  • Kunnus, KristjanSLAC, LCLS, Menlo Pk, CA 94025 USA. (author)
  • Robinson, Joseph S.SLAC, LCLS, Menlo Pk, CA 94025 USA. (author)
  • Hampton, Christina Y.SLAC, LCLS, Menlo Pk, CA 94025 USA. (author)
  • Hoffman, David J.SLAC, LCLS, Menlo Pk, CA 94025 USA. (author)
  • Koralek, JakeSLAC, LCLS, Menlo Pk, CA 94025 USA. (author)
  • Loh, Zhi-HengNanyang Technol Univ, Sch Chem Chem Engn & Biotechnol, Singapore 637371, Singapore.;Nanyang Technol Univ, Sch Phys & Math Sci, Singapore 637371, Singapore. (author)
  • Santra, RobinDeutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.;Univ Hamburg, Dept Phys, D-22607 Hamburg, Germany. (author)
  • Inhester, LudgerDeutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany. (author)
  • Young, LindaArgonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.;Univ Chicago, Dept Phys, Chicago, IL 60637 USA.;Univ Chicago, James Franck Inst, Chicago, IL 60637 USA. (author)
  • Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany.Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA. (creator_code:org_t)

Related titles

  • In:Journal of the American Chemical Society: American Chemical Society (ACS)146:5, s. 3262-32690002-78631520-5126

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